Table of contents

VEIT 2017

The International Summer School on Vacuum, Electron and Ion Technologies (VEIT) has been organized biennially since 1978, when the series of VEIT Schools was launched by the Institute of Electronics, Bulgarian Academy of Sciences, with the aim to act as a forum for exchange and dissemination of knowledge and ideas on the latest developments in electron-, ion-, and plasma-assisted technologies. The organizers of the 2017 edition of the event were the Institute of Electronics, Bulgarian Academy of Sciences, Sofia, Bulgaria and the Dutch Institute for Fundamental Energy Research, Eindhoven, The Netherlands. While the school has initially been providing a meeting place for researchers mainly from Eastern and Central European countries, its importance has grown issue by issue. The school is now a major scientific event and a meeting place for young scientists from Eastern and Western Europe involved in research and development associated with high-tech industries. Many former school participants have gone on to become leading scientists in research establishments and companies throughout the world. Leading international companies, such as High Voltage Engineering, Balzers, Varian, and Hauzer have used the VEIT forum to present their products through oral presentations, poster contributions or exhibits. The School Proceedings have been published in special issues of the international journals Vacuum, Plasma Processes and Polymers, Journal of Physics: Conference Series.

The twentieth jubilee edition of VEIT was held in the Black Sea resort Sozopol, Bulgaria, from 25 to 29 September 2017. It was attended by 149 participants (36 students and young researchers) from 20 countries on three continents: Austria, Bulgaria, France, Germany, Iran, Japan, Mexico, Portugal, Romania, Russia, Spain, Serbia, Slovakia, Slovenia, Sweden, The Czech Republic, The Netherlands, Ukraine, UK, USA.

List of conference are available in this PDF.

All papers published in this volume of Journal of Physics: Conference Series have been peer reviewed through processes administered by the proceedings Editors. Reviews were conducted by expert referees to the professional and scientific standards expected of a proceedings journal published by IOP Publishing.

Gyrotrons are the most powerful sources of CW coherent radiation in the sub-THz and THz frequency bands. In recent years, they have demonstrated a remarkable potential for bridging the so-called THz-gap in the electromagnetic spectrum and opened the road to many novel applications of the terahertz waves. Among them are various advanced spectroscopic techniques (e.g., ESR and DNP-NMR), plasma physics and fusion research, materials processing and characterization, imaging and inspection, new medical technologies and biological studies. In this paper, we review briefly the current status of the research in this broad field and present our problem-oriented software packages developed recently for numerical analysis, computer-aided design (CAD) and optimization of gyrotrons.

We present a model for hole-mediated spontaneous breakdown of ahomoepitaxial two-dimensional (2D) flat nanowire based exclusively on random, thermally-activated motion of atoms. The model suggests a consecutive three-step mechanism driving the rupture and complete disintegration of the nanowire on a crystalline surface. The breakdown scenario includes: (i) local narrowing of a part of the stripe to a monatomic chain, (ii) formation of a recoverable single vacancy or a 2D vacancy cluster that causes temporary nanowire rupture, (iii) formation of a non-recoverable 2D hole leading to permanent nanowire breakdown. These successive events in the temporal evolution of the nanowire morphology bring the nanowire stripe into an irreversible unstable state, leading to a dramatic change in its peculiar physical properties and conductivity. The atomistic simulations also reveal a strong increase of the nanowire lifetime with an enlargement of its width and open up a way for a fine atomic-scale control of the nanowire lifetime and structural, morphological and thermodynamic stability.

In this work, laser-induced breakdown spectroscopy was applied to determining the elemental composition of a set of ancient bronze artefacts dated from the Late Bronze Age and Early Iron Age (14^th – 10^th century BC). We used a Nd:YAG laser at 1064 nm with pulse duration of 10 ns and energy of 10 mJ and determined the elemental composition of the bronze alloy that was used in manufacturing the samples under study. The concentrations of tin and lead in the bulk of the examined materials was estimated after generating calibration curves for a set of four standard samples. The preliminary results of the analysis will provide information on the artefacts provenance and on the production process.

We propose a novel use of an optical cell of micrometer thickness filled with Cs vapor in view of studying the collisions between two different alkali atoms of strongly different densities. We demonstrate narrow and good-contrast sub-Doppler resonances at the Rb D₂ line for a mean-free-path of the Cs atoms comparable to the optical cell longitudinal dimension; the resonances are completely destroyed when the mean-free-path of the Cs atoms is more than two orders of magnitude shorter than the longitudinal dimension of the thin cell.

We used schlieren photography to visualize the influence of gas flow rates of 1, 2.5, 5, 10 L/min and of the applied voltage frequency on a helium atmospheric plasma jet induced at the nozzle of a capillary tube. The expansion of the gas in the surrounding medium (air) was analyzed in the two different modes – plasma on/plasma off. Changes in the above parameters affect the gas flow regime and the hydrodynamics of the jet.

Optogalvanic (OG) interaction is simulated and studied in a segmented hollow-cathode discharge (SHCD). HCD-lamps are used to induce an OG signal by their own emission or by that of another lamp. The efficiency of the OG of a Ne/Cu HCD lamp in the range 320-380 nm is estimated theoretically. An irregular galvanic peak arising near the inflection point in the i-V curve (∂V/∂i<0) is detected. Its origin is related to Penning ionization of the sputtered cathode material.

We propose a way of achieving efficient and robust second-harmonic generation. The technique proposed is similar to the adiabatic population transfer in a two-state quantum system with crossing energies. If the phase mismatching changes slowly, e.g., due to a temperature gradient along the crystal, and makes the phase match for second-harmonic generation to occur, then the energy would be converted adiabatically to the second harmonic. As an adiabatic technique, the second-harmonic generation scheme presented is stable to variations in the crystal parameters, as well as in the input light, crystal length, input intensity, wavelength and angle of incidence.

Using the well-known Wassiljewa equation and a new simple method, the thermal conductivities of various 2- and 3-component gas mixtures were calculated and compared under gas-discharge conditions optimal for two prospective lasers excited in a nanosecond pulsed longitudinal discharge. By solving the non-stationary heat-conduction equation for electrons, a 2D numerical model was also developed for determination of the radial and temporal dependences of the electron temperature T_e(r, t).

Neutral particle analyzers (NPA) measure line-integrated energy spectra of fast neutral atoms escaping the tokamak plasma, which are a product of charge-exchange (CX) collisions of plasma ions with background neutrals. They can observe variations in the ion temperature T_i of non-thermal fast ions created by additional plasma heating. However, the plasma column which a fast atom has to pass through must be sufficiently short in comparison with the fast atom's mean-free-path. Tokamak COMPASS is currently equipped with one NPA installed at a tangential mid-plane port. This orientation is optimal for observing non-thermal fast ions. However, in this configuration the signal at energies useful for T_i derivation is lost in noise due to the too long fast atoms' trajectories. Thus, a second NPA is planned to be connected for the purpose of measuring T_i. We analyzed different possible view-lines (perpendicular mid-plane, tangential mid-plane, and top view) for the second NPA using the DOUBLE Monte-Carlo code and compared the results with the performance of the present NPA with tangential orientation. The DOUBLE code provides fast-atoms' emissivity functions along the NPA view-line. The position of the median of these emissivity functions is related to the location from where the measured signal originates. Further, we compared the difference between the real central T_i used as a DOUBLE code input and the T_iCX derived from the exponential decay of simulated energy spectra. The advantages and disadvantages of each NPA location are discussed.

A one-dimensional two-fluid model of the plasma-wall transition in front of a large, negative, planar electrode is presented. The electrons are assumed to be isothermal, while for the ions the closure is made by the assumption that the ion heat flux is proportional to the negative gradient of the ion temperature. The introduction of the ion heat flow into the model changes the ion flow towards the electrode from mainly adiabatic into almost isothermal.

This work deals with the determination of reliable transport and equilibrium thermophysical properties of binary mixtures of O₂ and the noble gases Ar, Kr, and Xe. The second virial coefficients B(T), the viscosities η(T), and the binary diffusion coefficients D₁₂(T) were calculated for each mixture in the temperature range between 200 K and 1000 K using a a temperature dependent (n-6) Lennard-Jones intermolecular interaction potential model. The properties of the mixtures were obtained by using the Lorentz-Berthelot and Hohm-Zarkova-Damyanova mixing rules. Our results were compared to other theoretical and experimental data and acceptable agreement was found in all cases. Fitting formulae for the calculation of the intermolecular potential parameters and equilibrium and transport properties of the examined mixtures are recommended proposed.

In this report, the distribution of and deviation in the electric field were investigated in the active medium of a TE CO₂ laser. The variation in the electric field is due to injection of net electron and proton charges as a plasma generator. The charged-particles beam density is assumed to be Gaussian. The electric potential and electric field distribution were simulated by solving Poisson's equation using the SOR numerical method. The minimum deviation of the electric field obtained was about 2.2% and 6% for the electrons and protons beams, respectively, for a charged-particles beam-density of 10⁶ cm^-3. This result was obtained for a system geometry ensuring a mean-free-path of the particles beam of 15 mm. It was also found that the field deviation increases for a the mean-free-path smaller than that or larger than 25 mm. Moreover, the electric field deviation decreases when the electrons beam density exceeds 10⁶ cm^-3.

In the present work, we examined the patterns of the electron beam motion when controlling the transverse with respect to the axis of the beam homogeneous magnetic field created by the coils of the deflection system the electron gun. During electron beam processes, the beam motion is determined the process type (welding, surface modification, etc.), the technological mode, the design dimensions of the electron gun and the shape of the processed samples. The electron beam motion is defined by the cumulative action of two cosine-like control signals generated by a functional generator. The signal control is related to changing the amplitudes, frequencies and phases (phase differences) of the generated voltages. We realized the motion control by applying a graphical user interface developed by us and an Arduino Uno programmable microcontroller. The signals generated were calibrated using experimental data from the available functional generator. The free and precise motion on arbitrary trajectories determines the possible applications of an electron beam process to carrying out various scientific research tasks in material processing.

The ISO/IEC 62264 standard is widely used for integration of the business systems of a manufacturer with the corresponding manufacturing control systems based on hierarchical equipment models, functional data and manufacturing operations activity models. In order to achieve the integration of control systems, formal object communication models must be developed, together with manufacturing operations activity models, which coordinate the integration between different levels of control. In this article, the development of integrated control system for electron beam welding process is presented as part of a fully integrated control system of an electron beam plant, including also other additional processes: surface modification, electron beam evaporation, selective melting and electron beam diagnostics.

The paper proposes an empirical modeling approach to the prediction followed by optimization of the exact shape of the cross-section of a welded seam, as obtained by electron beam welding. The approach takes into account the electron beam welding process parameters, namely, electron beam power, welding speed, and distances from the magnetic lens of the electron gun to the focus position of the beam and to the surface of the samples treated. The results are verified by comparison with experimental results for type 1H18NT stainless steel samples. The ranges considered of the beam power and the welding speed are 4.2 – 8.4 kW and 3.333 – 13.333 mm/s, respectively.

The paper reports result of residual stress distribution studies in CT specimens reconstituted by electron beam welding (EBW). The main aim of the study is evaluation of the applicability of the welding technique for CT specimens' reconstitution. Thus, the temperature distribution during electron beam welding of a CT specimen was calculated using Green's functions and the residual stress distribution was determined experimentally using neutron diffraction. Time-of-flight neutron diffraction experiments were performed on a Fourier stress diffractometer at the IBR-2 fast pulsed reactor in FLNP JINR (Dubna, Russia). The neutron diffraction data estimates yielded a maximal stress level of ±180 MPa in the welded joint.

The narrow-band coherent N-type resonance, promising for the development of advanced atomic clocks, can be considered as a type of three-photon resonance, where a two-photon Raman excitation is combined with a resonant optical pumping field. In this communication, we present an experimental study and a theoretical analysis related to three-photon, bi-chromatic excitation of Cs atomic vapor contained in an 8-mm long cell with 20 Torr of neon. If a coupling laser is fixed at a frequency that is lower by several GHz than the position of the absorption profile of the F_g = 4 set of transitions, and a probe laser is tuned over the D₂ line (λ = 852 nm), a narrow high-contrast enhanced absorption N-resonance will be observed in the probe light profile, superimposed on the absorption profile of the F_g = 4 set of transitions. We present theoretical modeling aimed to clarify the processes behind the efficiency of the N-resonance preparation for different frequency positions of the coupling laser within the D₂ line of Cs.

In this paper, we evaluate the optical response of a stack of two diffraction gratings of equal one-dimensional periodicity. The first one is a surface-relief grating structure; the second, a volume polarization grating. This model is based on our experimental results from polarization holographic recordings in azopolymer films. We used films of commercially available azopolymer (poly[1-[4-(3-carboxy-4-hydroxyphenylazo) benzenesulfonamido]-1,2-ethanediyl, sodium salt]), shortly denoted as PAZO. During the recording process, a polarization grating in the volume of the material and a relief grating on the film surface are formed simultaneously. In order to evaluate numerically the optical response of this "hybrid" diffraction structure, we used the rigorous coupled-wave approach (RCWA). It yields stable numerical solutions of Maxwell's vector equations using the algebraic eigenvalue method.

Azobenzene containing polymers (azopolymers) have been investigated for a number of applications – holographic data storage, polarization optical elements, diffractive gratings, etc. Herein we report on the optical characteristics of films obtained from the commercially available water soluble azopolymer PAZO (poly[1-[4-(3-carboxy-4-hydroxyphenylazo) benzenesulfonamido]-1,2-ethanediyl, sodium salt). Thin films were deposited by spin coating and their thickness was determined by a Talystep precision profilometer. The FTIR spectra of PAZO were measured between 3000 cm^-1 and 500 cm^-1. For the first time, to the best of our knowledge, we evaluated the PAZO complex refractive index continuously in a broad spectral range (320 – 800 nm) based on transmission and reflection spectrophotometric data. The wavelength dependence of the complex refractive index of organic dyes layers cannot be readily described with dispersion models used for crystals, metals or semiconductors. This is why we used a derivative approach on a wavelength-by-wavelength basis to solve a set of two nonlinear equations with two unknowns – the real and imaginary parts of the refractive index. The determination of the optical constants of PAZO films is effective and robust.

The photoinduced optical anisotropy (birefringence and dichroism) in azobenzene-containing materials gives rise to a variety of applications in photonics by way of controlling the anisotropic properties at a nanoscale level. These applications require modeling the photoisomerization process kinetics. This is a complex and stochastic task that depends on many parameters. The paper presents a computationally effective Monte-Carlo simulation of recording, relaxation and erasure of the photoinduced anisotropy for a large number of 3D-oriented molecules at small angular increments between the neighboring orientations. The modeling is in good agreement with the experiment for measuring the birefringence in the PAZO polymer.

The detected lidar return power is a basic factor determining the brightness of the detected lidar images and the signal-to-noise ratio (SNR) of a given measurement. At equal other characteristics, the laser radiation wavelength should influence the lidar return signal and assume an optimum value depending on the specificity of the objects investigated. As such a problem had not been considered systematically, we recently began developing a modeling approach to solving it, based on evaluating the mean and the noisy lidar profiles and the SNR profile of the measurement along the lidar line of sight by using the lidar equation and well known realistic models of the atmospheric objects and background. The main purpose of the present work is to estimate by numerical modeling the detectability of the lidar return from different distances and multilayer cirrus clouds, depending on the laser radiation wavelengths. The results obtained confirm the expectations that at a higher atmospheric turbidity, a relatively higher sensing efficiency (return power) is achievable by longer-wavelength laser radiation, within the NIR range.

Studies of and modeling the impact of natural UV irradiation on the human population are of significant importance for human activity and economics. The sharp increase of environmental problems – extraordinary temperature changes, solar irradiation abnormalities, icy rains – raises the question of developing novel means of assessing and predicting potential UV effects. In this paper, we discuss new UV irradiation modeling based on recent real-time measurements at Moussala Basic Environmental Observatory (BEO) on Moussala Peak (2925 m ASL) in Rila Mountain, Bulgaria, and highlight the development and initial validation of portable embedded devices for UV-A, UV-B monitoring using open-source software architecture, narrow bandpass UV sensors, and the popular Arduino controllers. Despite the high temporal resolution of the VIS and UV irradiation measurements, the results obtained reveal the need of new assumptions in order to minimize the discrepancy with available databases.

Linear and nonlinear absorption spectra of ¹³³Cs vapor confined in an extremely thin cell were computed via iterations with respect to the resonance radiation intensity. When the incident radiation intensity is low, the transient polarization of the atoms that undergo frequent collisions with the cell walls leads to sub-Doppler features in the absorption spectra. Higher incident radiation intensities result in the appearance of velocity-selective optical pumping resonances. The theory developed agrees quantitatively with the experimental findings.

This work presents an investigation of carbon formed on polycrystalline Cu(111) thin films prepared by ion beam sputtering at room temperature on c-plane Al₂O₃ after thermal treatment in a temperature range between 300 and 1020°C. The crystallinity of the Cu films was studied by XRD and RBS/channeling and the surface was characterised by Raman spectroscopy, XPS and AFM for each annealing temperature. RBS measurements revealed the diffusion of the Cu into the Al₂O₃ substrate at high temperatures of > 700°C. Furthermore, a cleaning procedure using UV ozone treatment is presented to remove the carbon from the surface which yields essentially carbon-free Cu films that open the possibility to synthesize graphene of well-controlled thickness (layer number).

We demonstrate the possibility to fabricate wire structures composed by arranged magnetic particles using pulsed laser deposition (PLD) in the presence of a magnetic field. Ablation of Ni and Co targets was performed in air by nanosecond laser pulses delivered by a Nd:YAG laser system oscillating at 355 nm. Due to the high density of the ambient, particles and clusters were formed by condensation in the plasma plume close to the target. The strong deceleration of the ablated material under these conditions further benefited the efficiency of applying a magnetic field to the plume. We also studied the effect of the target-to-substrate distance and the ambient pressure on the morphology of the deposited structures.

This paper reports on ZnO layers' sensitivity to NO₂ exposure. ZnO layers were grown by electrochemical deposition on the surface of quartz crystal microbalances (QCMs) with Au electrodes; the sensitivity was estimated by the frequency-time characteristics (FTCs) of the QCM, namely, its resonance-frequency-shift response. The sorption process was investigated in NO₂ test gas. The behavior was studied of three different sensors with ZnO layers deposited for different times – 30, 35 and 60 min. The change in the frequency, ΔF, of the QCM as a function of the loaded mass of NO₂ was detected in different NO₂ concentrations in the range of 250 – 5000 ppm and the value of the sorbed mass was calculated, together with the rate of the NO₂ sorption and desorption. As the time of ZnO layers deposition was increased, the sorbed NO₂ mass increased for all concentrations used in the experiment. This can be explained by changes in the ZnO layers' structure with the time of deposition.

We present the results of studies on the structural, optical and piezoelectric properties of ZnO thin films deposited by ALD on flexible polyethylene naphthalate (PEN) substrates. Changes were observed in the optical transmission and crystal structures as the deposition temperature was varied. The electromechanical behavior, dielectric losses and voltage generated from ZnO flexible devices were investigated and discussed, in order to estimate their suitability for potential application as microgenerators activated by human motion.

Different electrocatalysts were tested for oxidation of sulfites to sulfates, namely, manganese thin films deposited on fullerenes and carbon nanotubes. The results presented clearly show that electrodes containing HFs (higher fullerenes), DWCNTs (double-wall carbon nanotubes) and manganese acetate are effective catalysts in S/O₂ fuel cells. HFs and DWCNTs have high catalytic activity and can be employed as standalone catalysts. Manganese was deposited on DWCNTs, HFs and fullerenes C₆₀/C₇₀ by a thermal process. The electrocatalysts were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The electrochemical testing was carried out by plotting the E/V polarization curve. The polarization curves of the electrodes composed of pristine DWCNTs showed the lowest overpotentials.

We discuss the influence of the type of β-diketone ancillary ligand in Iridium (III) bis phenyl-benzothiazole complexes ((bt)₂Ir(β-diketone)) on their photophysical and electroluminescent properties when they are used as dopants in white organic light-emitting diodes (WOLED). For this purpose, we investigated four novel yellow cyclometalated complexes: (bt)₂Ir(dbm), (bt)₂Ir(fmtdbm), (bt)₂Ir(tta) and (bt)₂Ir(bsm), where dbm = 1,3-diphenylpropane-1,3-dionate; fmtdbm = 1-(4-fluorophenyl)-3-(4-methoxyphenyl)propane-1,3-dionate; tta = 4,4,4-trifluoro-1-(thiophene-2-yl)butane-1,3-dionate; and bsm = 1-phenylicosane-1,3-dionate). To obtain white light by mixing emissions of two complementary colors (yellow emitted by the dopant and blue, by another emitter), we chose the following OLED structure: ITO/doped HTL/ElL/ETL/M, where ITO was a transparent anode of In₂O₃:SnO₂; M, a metallic Al cathode; HTL, 4,4'-Bis(9H-carbazol-9-yl)biphenyl (CBP) involved in a poly(N-vinylcarbazole) (PVK) matrix; ElL, an electroluminescent layer of aluminum(III)bis(2-methyl-8-quninolinato)-4-phenylphenolate (BAlq); and ETL, an electron-transporting layer of zinc(II)bis(2-2-hydroxyphenyl)benzothiazole. We found that all complexes are suitable candidates for fabrication of WOLED. The best results were demonstrated by the device doped with 2 wt % of (bt)₂Ir(bsm), which had twice as high luminescence (1100 cd/m²) and one-and-a-half as high current efficiency (5 cd/A) as the device doped with 1.25 wt % of the known (bt)₂Ir(acac), with its 580 cd/m² and 3.4 cd/A at approximately the same CIE (Commission Internationale de L'Eclairage) (x/y) coordinates of the warm white light emitted by the two devices.

We prepared a set of Ti- and Cr-based ternary and quaternary hard coatings at low deposition temperatures (< 200 °C) by closed-field unbalanced magnetron sputtering in a gas mixture of Ar + N₂. The morphological, structural and mechanical properties of the coatings were characterized by means of atomic force microscopy, scanning electron microscopy, X-ray photoelectron spectrometry, a micro-scratch tester and a nanoindentation tester. The results of the analyses performed revealed that the surface of the deposited ternary Ti-Al-N coatings was rougher than that of the CrTiAlN coatings. The metallic elements in the coatings react with nitrogen to form CrN, TiN and AlN nitride phases, as no Cr₂N phase was detected in the Cr-based coatings. The optimized quaternary coating demonstrated mechanical properties superior to those of the ternary ones in terms of hardness; adherence strength of 32 GPa and elastic modulus of 418 GPa were measured for the multicomponent coating of composition Cr_0.68Ti_0.19Al_0.13N.

N-doped carbon thin films were deposited on a silicon substrate and quartz glass by RF reactive magnetron sputtering using a carbon target and an Ar+N₂ gas mixture. During the magnetron sputtering, the substrate holder temperatures was kept at 800 °C. The carbon film thickness on the silicon substrate was about 70 nm, while on the quartz glass it was in the range 15 nm – 60 nm. The elemental concentration in the films was determined by RBS and ERD. Raman spectroscopy was used to evaluate the intensity ratios I_D/I_G of the D and G peaks of the carbon films. The transmission photocathodes prepared were placed in the hollow-cathode assembly of a Pierce-structure DC gun to produce photoelectrons. The quantum efficiency (QE) was calculated from the laser energy and cathode charge measured. The properties of the transmission photocathodes based on semitransparent N-doped carbon thin films on quartz glass and their potential for application in DC gun technology are discussed.

The paper reports on the effect of the substrate temperature (350 °C, 380 °C and 420 °C) during reactive magnetron sputtering of a TiN film on the phase composition, texture and mechanical properties of TiN/TiO₂ coatings on 304L stainless steel substrates. Pure Ti was used as a cathode source of Ti. The texture and unit cell parameters of both TiN and TiO₂ phases of the coating are discussed in relation with the tribological properties and adhesion of the coating. The scratch tests performed showed that the nitride deposited at 380 °C, having the highest unit cell parameter and a predominant (111) texture, possessed the lowest friction coefficient (μ), tangential force and brittleness. The anatase-type TiO₂ with predominant (101) pole density and increased c unit cell parameter showed the highest stability on the nitride deposited at 420 °C. The results indicated that the friction coefficient, tangential force and critical forces of fracture could be varied by controlling the coating deposition temperature.

We report the results of a study on the optical and electrical properties of nanolaminate TiO₂/Pt/TiO₂ structures fabricated using RF magnetron sputtering. The effect was investigated of the discontinuous Pt layer on the optical transmittance, electrical conductivity and morphology of the TiO₂/Pt/TiO₂ structure. On the basis of the theory of electronic tunneling transport between metal granulates in a dielectric matrix, a new technological approach is proposed of preparing high-sensitivity strain sensors based on resistors with a nanolaminate structure containing Pt granulates.

The properties were studied of Ta, Ta₂O₅ and Ta/Ta₂O₅ coatings deposited by reactive magnetron sputtering on stainless steel (AISI 316) substrates. The compositional, structural and morphological parameters of the coatings were investigated by means of X-ray photoemission spectroscopy (XPS), energy dispersive X-ray (EDX) spectroscopy, and scanning electron microscopy (SEM). The roughness parameters, adhesion strength, hardness, elastic modulus, and H/E ratio were evaluated by standard techniques. The hardness parameters of the Ta₂O₅ and Ta/Ta₂O₅ coatings increased in comparison with pure Ta films, while the relatively low Young's modulus was related to high elastic recovery and high resistance to cracking. The tantalum-based coatings possessed good biomechanical parameters for advanced implant and stent applications.

The ion-beam assisted deposition (IBAD) is an advanced method capable of producing crystalline coatings at low temperatures. We determined the characteristics of hydroxyapatite Ca₁₀(PO₄)₆(OH)₂ target and coatings formed by IBAD using X-ray photoemission spectroscopy (XPS), X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM) and energy dispersive X-ray (EDX). The composition of the coatings' cross-section and surface was close to those of the target. The XPS spectra showed that the binding energy values of Ca (2p1/2, 2p3/2), P (2p3/2), and O 1s levels are related to the hydroxyapatite phase. The coatings demonstrate an optimal H/E ratio, and a good resistance to scratch tests.

Orthodontic archwires are among the most important devices of fixed orthodontic therapy. Many types of archwires are made available on the market by various manufacturers with different elemental composition and structural characteristics. Knowing this information is important when choosing a suitable archwire for a particular stage of orthodontic treatment. The aim of our study is to characterize a new type orthodontic archwires (TriTanium^TM, American Orthodontics) before their placement in the oral cavity. To achieve the aim, we used modern methods for determining their elemental composition and structural characteristics: laser-induced plasma spectroscopy (LIBS), X-ray diffraction analysis (XRD), scanning electronic microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and differential scanning calorimetry (DSC). The results obtained from the qualitative elemental analysis by LIBS and the quantitative elemental analysis by EDX showed that Ni and Ti are the main elements in the archwire studied. The room-temperature XRD patterns showed peaks typical for a Ni-Ti alloy with an austenite-type structure. Monitoring the phase transitions by means of DSC measurements in the temperature range from –50 °C to +50 °C, we showed that in TriTanium^TM archwires, besides the austenite to martensite transition, there exists a rhombohedral intermediate phase (R phase). This study will be useful in assisting orthodontists in applying appropriate nickel-titanium orthodontic archwires in the clinical practice.

The micelle formation of commercially available Pluronic PE 6800 (PEO-PPO-PEO triblock copolymer) was studied by means of a dye solubilization method, and the solubility of 1,6-diphenyl-1,3,5-hexatriene in aqueous solutions of the copolymer with concentrations ranging from 0.05 to 20 % w/v was studied by recording the transmission and emission spectra of the solutions using UV-VIS and photoluminescence spectroscopy, respectively. Further, mesoporous Nb₂O₅ films using PE 6800 micelles templates were obtained through sol-gel using spin-coating; their morphology, structure and optical properties were studied by TEM, SAED and nonlinear fitting of reflectance measurements. The possible application of the films in optical sensing of vapors was demonstrated and discussed.

The sol-gel and spin-coating methods were used for deposition of thin transparent V₂O₅ films on optical glass substrates and silicon wafers. Different synthesis and deposition conditions, including synthesis temperatures and post-deposition annealing, were used aiming at obtaining transparent films with high refractive index and good optical quality. The surface morphology and structure of the films were studied by SEM and XRD. The optical properties (refractive index, extinction coefficient and optical band gap) and thickness of the V₂O₅ films were determined from their transmittance and reflectance spectra. The potential application of the films as building blocks of optical sensors was demonstrated by preparation of multilayered structures comprising both V₂O₅ and BEA-type zeolite films and testing their response towards acetone vapors.

Antirelaxation coatings (ARC) are used in optical cells containing alkali metal vapor to reduce the depolarization of alkali atoms after collisions with the cell walls. The long-lived ground state polarization is a basis for development of atomic clocks, magnetometers, quantum memory, slow light experiments, precision measurements of fundamental symmetries etc. In this work, a simple method for measuring the number of collisions of the alkali atoms with the cell walls without atomic spin randomization (Nasyrov et al., Proc. SPIE (2015)) was applied to characterize the AR properties of two PDMS coatings prepared from different solutions in ether (PDMS 2% and PDMS 5%). We observed influence of the light-induced atomic desorption (LIAD) on the AR properties of coatings.

Polycrystalline mono-phase bismuth titanate was produced by free cooling from melts heated to 1170 °C. The control over the initial amounts in the starting compositions in the system Bi₂O₃/TiO₂/SiO₂/Nd₂O₃ and over the thermal gradient of the heat process resulted in the formation of specific structures and microstructures of monophase sillenite ceramics. The main phase Bi₁₂TiO₂₀ belongs to the amorphous network groups based on oxides of silicon, bismuth and titanium. In this work, we demonstrated a way to control the crystalline and amorphous phase formation in bulk poly-crystalline materials in the selected system.

We analyzed the electrical characteristics of MOS structures with a SiO_x layer grown on Si treated in plasma without heating. The hysteresis effect observed indicates the presence of traps spatially distributed into the oxide near the interface. The shift and the shape of the curves reveal a small oxide charge and low leakage currents, i.e. a high-quality dielectric layer. The generalized C-V curve was generated by applying the two-frequency methods on the C-V and G-V characteristics at frequencies in the range from 1 kHz to 300 kHz and by accounting for the series resistance and the leakage through the oxide layer. The energy spectra of the interface traps were calculated by comparing the experimental and the ideal theoretical C-V curves. The spectra showed the presence of interface traps with localized energy levels in the Si bandgap. These conclusions correlate well with the results on this oxide's mechanical stress level, composition and Si-O ring structure, as well as on the interfacial region composition, obtained by our previous detailed multi-angle spectral ellipsometric studies. The ellipsometric data and the capacitance in strong accumulation of the C-V curves were used to calculate the thickness and the dielectric constants of the oxide layers.

TiCN nanopowder deposited in an appropriate way on the surface of an AlSi₁₂Cu₂NiMg substrate was incorporated in the matrix using an electron beam technology. The samples were studied by means of light microscopy, SEM, and EDX; their microhardness was also determined. The formation was found of a uniform and dense coating with a thickness of 7 – 10 μgm with a good adherence to the substrate. A modified zone appeared under the coating with a thickness of 100 – 150 μgm containing dendrites of an α-solid solution and a fine eutectic between them, as well as primary silicon crystals. The microhardness of this modified zone was up to 2.4 times higher than that of the matrix. The results of SEM and EDX studies revealed unambiguously the presence of titanium in the coating and in the zones below it. Obviously, the electron beam treatment resulted in the TiCN nanoparticles penetrating into the coating and the substrate immediately below the coating.

We studied the degradation of different types of bulk heterojunction devices, in which the materials comprising the active layer and/or the materials used for the back electrode are varied. The devices are deposited on ITO covered glass and have the structure PEDOT:PSS/BHJ/Me, where PEDOT:PSS is the hole transport layer, BHJ (bulk heterojunction) is the active layer comprising a polymer donor (e.g. PTB7, PCDTBT) and a fullerene derivative acceptor (e.g. PC60BM, PC70BM) deposited by spin coating, Me is the metal back contact, which is either Ag or Al deposited by magnetron sputtering or thermal evaporation. The device performance was monitored after storage in the dark at ambient conditions by following the evolution of the J-V curve over time. Results of real conditions outdoor degradation studies are also presented. The stability of the different solar cell structures studied is compared.

Ni doping induces modifications and considerable changes in the optical, electrical and magnetic properties of ZnO films. In this work, the influence is discussed of Ni-doping (two nickel concentrations) and annealing temperature (ranging from 300 ° C to 800 °C) on the structural and optical properties of sol-gel derived ZnO:Ni films. Uniform and smooth films were obtained by spin-coating on quartz and Si substrates. The ZnO:Ni films were crystallized in wurtzite phase with no impurity phases found for annealing temperatures up to 600 °C. The size of the crystallites was strongly affected by the Ni content and the heat treatment. Furthermore, the Ni doping improved the optical transparency of the sol-gel films, while the AFM studies showed that the film morphology and the roughness were influenced by the nickel doping.

In this contribution, we apply impedance spectroscopy (IS) to study a series of bulk-heterojunction PCDTBT:PC70BM solar cells deposited by spin-coating from dichlorobenzene solution of different concentrations. The samples are deposited on ITO covered glass and have the structure PEDOT:PSS / PCDTBT:PC70BM / Me where Me is Ag or Al deposited by either magnetron sputtering or thermal evaporation. The impedance spectra are measured upon one sun illumination at short-circuit conditions as a function of the concentration of the solution used for the deposition of the active layer. For one of the samples, measurements are made as a function of the applied bias as well. The measured spectra are fitted using an equivalent circuit. The dependences of the parameters derived from the fits on the concentration of the solution and on the bias voltage are presented and discussed in correlation with the quality of the solar cells.

The paper presents results on nanosecond laser ablation of thin films immersed in a liquid. The thin films were prepared by consecutive deposition of layers of different metals by thermal evaporation (first layer) and classical on-axis pulsed laser deposition (second layer); Ni/Au, Ag/Au and Ni/Ag thin films were thus deposited on glass substrates. The as-prepared films were then placed at the bottom of a glass vessel filled with double distilled water and irradiated by nanosecond laser pulses delivered by a Nd:YAG laser system at λ = 355 nm. This resulted in the formation of colloids of the thin films' material. We also compared the processes of ablation of a bulk target and a thin film in the liquid by irradiating a Au target and a Au thin film by the same laser wavelength and fluence (λ = 355 nm, F = 5 J/cm²). The optical properties of the colloids were evaluated by optical transmittance measurements in the UV– VIS spectral range. Transmission electron microscopy was employed to estimate the particles' size distribution.

We present results on laser-induced color changes in gold- and silver-doped glass. The doped borosilicate glass was prepared by conventional melt quenching. The study was focused on the change of the optical properties after irradiation of the glass by femtosecond laser pulses. Under certain conditions, the laser radiation induces defects associated with formation of color centers in the material. We studied this process in a broad range of laser radiation wavelengths – from UV to IR, and observed changes in the color of the irradiated areas after annealing of the processed glass samples, the color being red for the gold-doped glass red and yellow for the silver-doped glass. The structural and morphological analyses performed indicated that this effect is related to formation of metal nanoparticles inside the material. The results obtained show that femtosecond laser processing of noble-metal-doped glasses can be used for fabrication of 3D-nanoparticles systems in transparent materials with application as novel optical components.

Fibrous 3D matrices were fabricated from poly--caprolactone (PCL) by fused deposition modeling. Femtosecond laser irradiation was then used to demonstrate the possibility to affect the porosity of the 3D PCL fiber meshes. The surface characteristics were analyzed by scanning electron microscopy (SEM) and confocal microscopy. The interrelationship was examined between the laser processing parameters (number of pulses, pulse energy applied) and the response of the biomaterial. The formation was demonstrated of well-defined micropores, while the original fiber structure was retained. The study of cells cultivation on the laser-modified scaffolds showed good adhesion compared to a non-modified scaffold. The results obtained showed that femtosecond laser processing can be used as an alternative non-contact tool in enhancing the porosity of artificial constructs, thus influencing the cell adhesion into fibrous meshes.

In this work, ZnO nanostructures were fabricated on Ag-coated substrates by pulsed laser deposition. Ag was incorporated into ZnO nanostructures during the growth by using a composite, or mosaic, target. The effect was studied of Ag doping on the morphology, structure, composition, and photoluminescence of the ZnO nanostructures. It was found that the increase of the dopant concentration leads to a deterioration of the crystalline structure, as well as to a change of the sample morphology. It was also found that the manner of incorporating Ag into the ZnO matrix affects the photoluminescent performance of the nanocomposite coatings.

This study deals with the development of a novel technique for formation of advanced Ag nanostructures (NSs) to be applied to high-resolution analyses based on surface enhanced Raman scattering (SERS). It has direct bearing on human health and food quality, e.g., monitoring small amount or traces of pollutants or undesirable additives. Three types of nanostructured Ag samples were produced using ion-beam deposition at glancing angle (GLAD) on quartz. All fabricated structures were covered with BI-58 pesticide (dimethoate) or Rhodamine 6G (R6G) for testing their potential for use as substrates for (SERS).

The medical-grade polydimethylsiloxane (PDMS) elastomer is a widely used biomaterial in medicine for preparation of high-tech devices because of its remarkable properties. In this paper, we present experimental results on surface modification of PDMS elastomer by using ultraviolet, visible, and near-infrared ns-laser system and investigation of the chemical composition and the morphological structure inside the treated area in dependence on the processing parameters – wavelength, laser fluence and number of pulses. Remarkable chemical transformations and changes of the morphological structure were observed, resulting in the formation of a highly catalytically active surface, which was successfully functionalized via electroless Ni and Pt deposition by a sensitizing-activation free process.

The results obtained are very promising in view of applying the methods of laser-induced micro- and nano-structuring and activation of biopolymers' surface and further electroless metal plating to the preparation of, e.g., multielectrode arrays (MEAs) devices in neural and muscular surface interfacing implantable systems.

The properties of a La_0.67Sr_0.33MnO₃ (LSMO)/YBa₂Cu₃O_7-δ (YBCO) interface in thin film LSMO/YBCO cross-strip type junctions were investigated by means of electrical transport measurements. Resistance vs. temperature and current-voltage dependences, as well as conductance spectra, were used to characterize the electrical parameters of the interface. The results indicated a low resistance (below 10 Ω), while the dielectric properties of the interface pointed to the presence of a 10-nm wide and 40-meV high dielectric potential barrier. The oxygen vacancies in both LSMO and YBCO films at the interface and the charge transfer through the interface were both considered to explain the insulating character of the LSMO/YBCO interface.

Three-component surface alloys of the Ti-Al-Nb and Ti-Al-V systems were formed by means of selective electron beam alloying; the procedure involved DC magnetron sputtering deposition of multilayer Al and Nb or Al and V films with a thickness of 1 μm of each layer on a commercially-pure Ti substrate. The samples prepared were then electron-beam surface-alloyed under identical technological conditions. The specimens were examined by scanning electron microscopy (SEM); their chemical composition was studied by energy dispersive X-ray spectroscopy (EDX). X-ray diffraction (XRD) was used to determine the crystallographic structure. Intermetallic alloys in the system of Ti-Al-V were successfully produced with an electron beam current of 15 mA. As the current was increased from 15 mA to 20 mA, only pure titanium was visible, probably due to the evaporation of the alloying materials. In the Ti-Al-N system, intermetallic alloys were formed when the electron beam current reached 25 mA.

The paper presents a technology for preparation and characterization of titanium dioxide (TiO₂) thin films suitable for gas sensor applications. Applying atomic layer deposition (ALD), very thin TiO₂ films were deposited on quartz resonators, and their gas sensing properties were studied using the quartz crystal microbalance (QCM) method. The TiO₂ thin films were grown using Ti(iOPr)₄ and water as precursors. The surface of the films was observed by scanning electron microscopy (SEM), coupled with energy dispersive X-ray analysis (EDX) used for a composition study. The research was focused on the gas-sensing properties of the films. Films of 10-nm thickness were deposited on quartz resonators with Au electrodes and the QCMs were used to build highly sensitive gas sensors, which were tested for detecting NO₂. Although very thin, these ALD-grown TiO₂ films were sensitive to NO₂ already at room temperature and could register as low concentrations as 50 ppm, while the sorption was fully reversible, and the sensors could be fully recovered. With the technology presented, the manufacturing of gas sensors is simple, fast and cost-effective, and suitable for energy-effective portable equipment for real-time environmental monitoring of NO₂.

We report studies on the mechanical response and deformation behavior of heat-treated nanoporous anodic alumina using a micro-balance test and experimental test equipment especially designed for this purpose. AAO samples were characterized mechanically by a three-point bending test using a micro-analytical balance. The deformation behavior was studied by repetitive mechanical bending of the AAO membranes using an electronically controlled system. The nanoporous AAO structures were prepared electrochemically from Al sheet substrates using a two-step anodizing technique in oxalic acid followed by heat treatment at 700 °C in air. The morphological study of the aluminum oxide layer after the mechanical tests and mechanical deformation was conducted using scanning electron and optical microscopy, respectively. The experimental results showed that the techniques proposed are simple and accurate; they could, therefore, be combined to constitute a method for mechanical stability assessment of nanostructured AAO films, which are important structural components in the design of MEMS devices and sensors.

Polarization holographic gratings (PHG) were recorded using a laser emitting a wavelength of 491 nm in thin films of the (poly[1-[4-(3-carboxy-4-hydroxyphenylazo)benzenesulfonamido]-1,2-ethanediyl, sodium salt]) azopolymer, shortly denoted as PAZO. Thin azopolymer films with various thicknesses were spin-coated on plastic and glass substrates. Four different polarization states of the recording beams were used, and the results compared: a) two vertical linear polarizations, b) horizontal and vertical linear polarizations, c) linear polarizations at +45° and –45° relative to the recording plane, and d) two orthogonal circular polarizations – left- and right-handed (LCP and RCP). The diffraction efficiency in the +1 diffraction order was monitored in real time by a probing laser beam at the wavelength of 635 nm. The results indicate that the highest diffraction efficiency is achieved when recording with orthogonal polarizations – linear at ±45° or left and right circular. This is explained by the ability of the azopolymer material to record the variations in the polarization state of light better than the variations in its intensity. The holographic gratings obtained can be used to enhance the light-extraction efficiency of an OLED device.

Experimental and simulation results are presented and discussed on electron-beam lithography (EBL) nano-structuring using the positive chemically semi-amplified electron-beam resist AR-P 6200 (CSAR 62), which provides high sensitivity and allows achievement of high resolutions (sub-100 nm). The influence of the e-beam lithography process parameters, namely, exposure dose, development process conditions, and proximity effects on the obtained developed images was studied for the case of 40-keV electron energy.

We report studies of the structural and microstructural properties of Sr₃Co₂Fe₂₄O₄₁ in bulk form and as thick films. The precursor powders for the bulk form were prepared following the sol-gel auto-combustion method. The prepared pellets were synthesized at 1200 °C to produce Sr₃Co₂Fe₂₄O₄₁. The XRD spectra of the bulks showed the characteristic peaks corresponding to the Z-type hexaferrite structure as a main phase and second phases of CoFe₂O₄ and Sr₃Fe₂O_7-x. The microstructure analysis of the cross-section of the bulk pellets revealed a hexagonal sheet structure. Large areas were observed of packages of hexagonal sheets where the separate hexagonal particles were ordered along the c axis. Sr₃Co₂Fe₂₄O₄₁ thick films were deposited from a suspension containing the Sr₃Co₂Fe₂₄O₄₁ powder. The microstructural analysis of the thick films showed that the particles had the perfect hexagonal shape typical for hexaferrites.

The influence was studied of 22-MeV electron irradiation on Si-SiO₂ structures implanted with high-fluence Si⁺ ions. Our earlier works demonstrated that Si redistribution is observed in Si⁺-ion-implanted Si-SiO₂ structures (after MeV electron irradiation) only in the case when ion implantation is carried out with a higher fluence (10¹⁶ cm^-2). We focused our attention on the interaction of high-dose MeV electron irradiation (6.0×10¹⁶ cm^-2) with n-Si-SiO₂ structures implanted with Si⁺ ions (fluence 5.4×10¹⁶ cm^-2 of the same order magnitude). The redistribution of both oxygen and silicon atoms in the implanted Si-SiO₂ samples after MeV electron irradiation was studied by Rutherford back-scattering (RBS) spectroscopy in combination with a channeling technique (RBS/C). Our results demonstrated that the redistribution of oxygen and silicon atoms in the implanted samples reaches saturation after these high doses of MeV electron irradiation. The transformation of amorphous SiO₂ surface into crystalline Si nanostructures (after MeV electron irradiation) was evidenced by atomic force microscopy (AFM). Silicon nanocrystals are formed on the SiO₂ surface after MeV electron irradiation. The shape and number of the Si nanocrystals on the SiO₂ surface depend on the MeV electron irradiation, while their size increases with the dose. The mean Si nanocrystals height is 16-20 nm after irradiation with MeV electrons at the dose of 6.0×10¹⁶ cm^-2.

The objective of this study is to examine long-term effects of low-level laser therapy (LLLT) in patients with autosomal dominant cone-rod dystrophy (CRDs). A He-Ne Laser with continuous emission at 633 nm (01 mW/cm²) was used on five patients with autosomal dominant pedigree of Romani origin with non-syndromic CRDs. The laser radiation was applied transpupillary to the macula six times for three minutes every other day. The experiment was conducted for a period of three years. The clinical evaluation included best corrected visual acuity determination, funduscopy, Humphrey perimetry, Farnsworth Hue-28 color testing, fluorescein angiography, and full-field electroretinogram (ERG).

All affected individuals presented reduced visual acuity (0.01 – 0.4) and photophobia. The funduscopic examination and fluorescein angiography revealed advanced changes including bone spicule-like pigment deposits in the midperiphery and the macular area, along with retinal atrophy, narrowing of the vessels, and waxy optic discs. The visual fields demonstrated central scotoma. The electrophysiologic examination of the patients detected an abnormal cone-rod ERG (20 – 30 μV) with photopic amplitudes more markedly reduced than the scotopic. Flicker responses were missing and Farnsworth Hue-28 test found protanopia. There was a statistically significant increase in the visual acuity (p<0.001, end of study versus baseline) for CRDs patients for the period of three years after the treatment with LLLT. Following the LLLT, the central absolute scotoma in CRDs was reduced, as was the prevalence of metamorphopsia in CRDs.

This study shows that LLLT may prove be a novel long-lasting therapeutic option for both forms of CRDs. It is a highly effective treatment resulting in a long-term improvement of the visual acuity.

The objective of this study was to examine long-term effects of low-level laser therapy (LLLT) in patients with age-related macular degeneration (AMD). The research was implemented for a period of five years. For LLLT, a He-Ne Laser with continuous emission at 633 nm (0.1 mW/cm²) was used in patients with AMD of all stages (dry to wet exudative forms were included). In total, 33 patients (16 men and 17 women – 66 eyes) with AMD of various stages and a mean age of 68.7 ± 4.2 years were included in the study. Progressive, exudative AMD was diagnosed in 8 eyes. 58 eyes had drusen or were depigmented. Laser radiation was applied transpupillary to the macula for six times for three minutes once in two days; 22 patients with AMD (44 eyes) were randomly selected to receive mock treatment (control group 10 men and 12 women with a mean age of 69.3 ± 4.8 years). The visual acuity was followed for a five-year period. The perimetry and Amsler test were used to screen central scotomas. The fluorescein angiography of AMD and the control groups was examined. The visual acuity remained unchanged in all patients in the control group. There was a statistically significant increase in the visual acuity (p<0.001, end of study versus baseline) for AMD patients for the period of five years after the treatment. The edema and hemorrhage in the patients with progressive, exudative AMD significantly decreased. No side effects were observed during the therapy. The prevalence of metamorphopsia, scotoma in AMD group was reduced.

In conclusion, this study shows that LLLT may be a novel long-lasting therapeutic option for both forms of AMD. It is a highly-effective treatment that results in a long-term improvement of the visual acuity.