Morphological and chemical structures of M33 are investigated with the LAMOST DR7 survey. Physical parameters; extinction; chemical composition of He, N, O, Ne, S, Cl, and Ar (where available); and radial velocities were determined for 110 nebulae (95 H ii regions and 15 planetary nebulae) in M33. Among them, 8 planetary nebulae and 55 H ii regions in M33 are newly discovered. We obtained the following O abundance gradients: − dex (based on 95 H ii regions), − dex (based on 93 H ii regions), and − dex (based on 21 H ii regions), utilizing abundances from N2 at O3N2 diagnostics and the Te-sensitive method, respectively. The He, N, Ne, S, and Ar gradients resulted in slopes of −, −, −, −, and −, respectively, utilizing abundances from the Te-sensitive method. Our results confirm the existence of the negative axisymmetric global metallicity distribution that is assumed in the literature. We noticed one new WC star candidate and one transition W-R WN/C candidate. The grand-design pattern of the spiral structure of M33 is presented.