Electrochemical Recovery of Gold from Waste Electric and Electronic Equipment Using Circulating Particulate Bed Reactor (CPBE)

The utilization of electrochemical process recovery involving low reactant concentrations of metal requires electrodes with high mass transport rates and specific surface areas. This is essential to increase cross-sectional current densities whilst optimizing the capital and operating costs. Experimental results demonstrated that Circulating Particulate Bed Reactor (CPBE) is suitable for the recovery of low concentrations of gold from aqueous chloride solution containing ${\mathrm{AuCl}}_{4}^{-}$ and ${\mathrm{AuCl}}_{2}^{-}$ of less than 0.5 mol m^-3(< 10² g m^-3). Elemental gold was successfully obtained on 0.5-1 mm gr particles in an electrochemical reactor incorporating a cation- permeable membrane and operated in bath recycle mode. Depletion to concentration < 5 × 10^-3 mol m^-3 (< 1 g m^-3) appeared to be mass transport controlled at an applied potential of +0.20 V (SCE), specific electrical energy consumption (SEEC) of ca. 800-1300 kWh h (tonne Au)^-1 for cell voltages (U) of 2.0-3.0 V, and fractional current efficiencies of ca. 0.95. However, atomic absorption and UV spectrophotometry established that as the $([{\mathrm{AuCl}}_{4}^{-}+[{\mathrm{AuCl}}_{2}^{-}])$ concentration decayed, the $[{\mathrm{AuCl}}_{4}^{-}]:[{\mathrm{AuCl}}_{2}^{-}]$ molar ratio changed. A multi-step mechanism for reduction of ${\mathrm{AuCl}}_{4}^{-}$ ions explained this behavior in terms of changing overpotentials for ${\mathrm{AuCl}}_{4}^{-}$ and ${\mathrm{AuCl}}_{2}^{-}$ reduction as total dissolved gold concentration decreased. In addition, SEM images confirmed that adherent and coherent Au deposits were achieved with CPBE for Au deposition under mass transport control at 0.20 V (SCE).