A compressed monolayer of CH3Cl adsorbed on graphite has
been examined by X-ray diffraction, EXAFS and molecular-dynamics
calculations (MD). A two-stage melting process with continuous melting in
one spatial direction (Tm = 147 K), followed by a second process, which
ultimately is discontinuous, has been found. The intermediate liquid state
at 147 K < T < 156 K, recently suggested on the basis of a specific-heat
measurement, has been identified as a liquid-crystal–like
phase. It has a high degree of orientational order of the dipolar molecules.