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The Japan Society of Applied Physics

The Japan Society of Applied Physics (JSAP) serves as an academic interface between science and engineering and an interactive platform for academia and the industry. JSAP is a "conduit" for the transfer of fundamental concepts to the industry for development and technological applications.

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Regular Paper

Demonstration of lateral field-effect transistors using Sn-doped β-(AlGa)2O3 (010)

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Published 4 March 2019 © 2019 The Japan Society of Applied Physics
, , Citation Hironori Okumura et al 2019 Jpn. J. Appl. Phys. 58 SBBD12

1347-4065/58/SB/SBBD12

Abstract

This paper demonstrates a modulation-doped fisseld-effect transistor (MODFET) and a metal-semiconductor field-effect transistor (MESFET) using β-(AlGa)2O3 (010). Ohmic contacts on Sn-doped (Al0.15Ga0.85)2O3 exhibit a fairly linear behavior, which has a specific contact resistivity and sheet resistance of 9 × 10−5 Ω cm2 and 75 kΩ/squ, respectively. The MODFET with Sn-doped (Al0.08Ga0.92)2O3 barrier layer showed a breakdown voltage of 610 V for gate-drain spacing (Lgd) of 8 μm, while the (Al0.16Ga0.85)2O3-channel MESFET exhibited a breakdown voltage of 940 V for Lgd of 20 μm. These results show the great potential of (AlGa)2O3 transistors for high-power applications.

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1. Introduction

Ga2O3 is an attractive material for high-power applications due to its high critical electric field Ec of 8 MV cm−1 and a band-gap energy above 4.5 eV.1,2) A β-gallia phase is the most thermally stable in Ga2O3. Bulk β-Ga2O3 is grown using melt growth techniques, such as edge-defined film-fed growth, providing low-cost large-scale wafers.35) The (010) orientation is typically preferred for current β-Ga2O3 device because homoepitaxial layers can be grown at a rate of 3 nm min−1 by plasma-assisted molecular-beam epitaxy (PAMBE).6,7)

β-Ga2O3 (010) has by now a well-established n-type doping technology. Si, Sn, and Ge are available as the n-type dopant.6,8,9) Ge-doped β-Ga2O3 (010) layers showed an electron mobility of 97 cm2 V−1 s−1 for a charge density of 2 × 1018 cm−3. Using n-type β-Ga2O3 (010), field-effect transistors (FETs) and Schottky-barrier diodes (SBDs) with a high breakdown voltage (Vbr) and low specific on-resistance (Ron) have been reported, e.g., trench metal-oxide-semiconductor SBDs with a reverse Vbr of 240 V and Ron of 2.9 mΩ cm2,10) field-plated SBDs with a reverse Vbr of 1076 V and Ron of 5.1 mΩ cm2,11) enhancement-mode fin FETs with an off-state Vbr of 612 V,12) and field-plated metal-oxide-semiconductor FETs (MOSFETs) with an off-state Vbr of 755 V.13) Recently, Ga2O3-based modulation-doped FETs (MODFETs) were demonstrated using a two-dimensional electron gas (2DEG) at the β-(AlGa)2O3/β-Ga2O3 (010) hetero-interface.14,15) Although most of the effort so far has focused on the development of β-Ga2O3 channel devices, the use of (AlGa)2O3 could enable even higher breakdown voltages and operating temperatures. In addtion to MODFETs, metal-semiconductor FETs (MESFETs) and MOSFETs are conceivable as the conventional lateral (AlGa)2O3 FETs. However, (AlGa)2O3 currently has some difficulties in crystal growth, leading to very few reports on the electrical properties of β-(AlGa)2O3 (010) channel devices.16,17)

In the β-(AlGa)2O3 (010) growth, one of the main challenges is related to the phase stability limits of Al2O3 in β-Ga2O3. Because Al2O3 prefers a corundum structure, the maximum Al content of β-(AlGa)2O3 (010) on Ga2O3 in PAMBE growth is limited to ~20%.15,18) n-type (AlGa)2O3 growth is even more difficult because dopants substitute Al atoms and/or segregate on the surfaces during growth.19) Recently, we achieved the pseudomorphic growth of n-type β-(Al0.16Ga0.84)2O3 layers on β-Ga2O3 (010) substrates via PAMBE.20) We used Sn as a dopant, unlike the other reports using Ge and Si.14,15) In this study, we report on the breakdown characteristics of MESFETs and MODFETs using Sn-doped β-(AlGa)2O3 with an Al content of 8%–16%.

2. Experimental procedures

For the devices, we used Fe-doped semi-insulating β-Ga2O3 (010) substrates with a miscut less than 0.2°. After solvent cleaning with acetone and methanol, the substrates were mounted on a SiC thermal-diffusion plate and were loaded into the MBE system. On the Ga2O3 substrate, the Sn-doped β-(AlGa)2O3/unintentional-doped (UID) β-(AlGa)2O3 (010) layers were grown at 700 ± 50 °C at the growth rate of 2 nm min−1. Research-grade O2 gas was supplied from an oxygen plasma source at a flow late of 0.5 sccm using radio-frequency plasma cell. The plasma power was maintained at 200 W. The substrate temperature was monitored using a pyrometer. Liquid Ga, Al, and SnO2 were thermally evaporated using effusion cells. The elemental beam equivalent pressure of Ga and Al were 1 × 10−6 and 5 × 10−7 Pa, respectively. The thickness and Al content of the (AlGa)2O3 layers were determined using Laue fringes and peak diffraction angle, respectively, from X-ray diffraction θ–2θ scans of the (020) plane.21) In reciprocal space mapping, the in-plane lattice constant for the (421)-diffraction peak of a 240 nm thick (Al0.16Ga0.84)2O3 layer stack corresponded to that of Ga2O3 substrates, indicating that the (Al0.16Ga0.84)2O3 layers are coherently grown on Ga2O3.

To investigate the breakdown characteristics of (AlGa)2O3-used devices, we fabricated MESFETs with an (AlGa)2O3-channel layer and MODFETs with a (AlGa)2O3 barrier layer. The (AlGa)2O3/Ga2O3 MODFETs reported so far in the literature used a delta doping in the (AlGa)2O3 barrier layer.14,15) These structures suffer from high contact resistance in the source/drain contacts due to the UID (AlGa)2O3 surface. We uniformly doped the whole (AlGa)2O3 barrier layer with Sn to reduce the contact resistance and increase the carrier concentration. The electron from donor atoms in the (AlGa)2O3 barrier layer spill over into the conduction band in the Ga2O3 channel layer, creating a 2DEG at the (AlGa)2O3/Ga2O3 interface. The processes for mesa isolation, ohmic contacts, and Schottky contacts in all (AlGa)2O3 FETs are as follows. A 150 nm deep mesa isolation was obtained by Cl2-based reactive-ion etching using Ni (50 nm) mask. After removing Ni metal using Piranha (H2SO4:H2O2 = 3:1), Ti (20 nm)/ Au (50 nm) metal stacks were deposited using an electron-beam evaporation for source/drain contacts, followed by annealing at 500 °C for 30 s in a nitrogen ambient to form metal alloy. A Ni (30 nm)/Au (50 nm) metal stack was then deposited for gate contact. Breakdown-voltage measurements were performed using an Agilent B1505A power-device analyzer and a high-voltage Tesla probe station. During breakdown measurements, the devices were immersed in a Fluorinert FC-770 solution to avoid surface flashover.

3. Results and discussion

3.1. Electrical property of Sn-doped (AlGa)2O3

Transmission line measurement (TLM) structures were made with Ti/Au contacts separated by various source-drain spacings (Lsd) on 100 nm thick heavily Sn-doped (Al0.15Ga0.85)2O3/100 nm thick UID (Al0.15Ga0.85)2O3 layers. The net donor concentration of the Sn-doped (AlGa)2O3 layer is estimated to be 2 × 1018 cm−3 at room temperature from capacitance–voltage (C–V) measurements. The current–voltage characteristics of the Sn-doped (AlGa)2O3 layer for various Lsd at room temperature are shown in Fig. 1(a). The Sn-doped (AlGa)2O3 layers were conductive and were electrically isolated by the bottom UID (AlGa)2O3 layers. The current showed a fairly ohmic behavior and increased with decreasing Lsd. In TLM, the specific contact resistance Rc and sheet resistance Rsh can be estimated by fitting the resistance values against Lsd and extrapolating the fitted line to a resistor of zero length. Rc of the (AlGa)2O3 layer is 9 × 10−5 Ω cm2, which is close to that of the reported Ga2O3 layers with donor concentrations of ~1018 cm−3.6,22,23) Rsh of the (AlGa)2O3 layer is 75 kΩ/squ, which is much higher in comparison with the reported Ga2O3 layers with 4.9 kΩ/squ.23) The electron mobility μe in the 100 nm thick (Al0.15Ga0.85)2O3 layer is calculated to be 4 cm2 V−1 s−1 by assuming that the donor concentration corresponds to electron concentration. Further growth optimization is necessary to increase the mobility.

Fig. 1.

Fig. 1. (Color online) (a) Current–voltage characteristics of Sn-doped (Al0.15Ga0.85)2O3 with a donor concentration of 2 × 1018 cm−3 for various source-drain spacings. (b) Two-terminal buffer-leakage breakdown voltage of unintentionally doped (Al0.15Ga0.85)2O3 (dash) and Ga2O3 (solid) as a function of source-to-drain spacing.

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The lateral Vbr of the UID (Al0.15Ga0.85)2O3 and Ga2O3 layers was measured between source and drain contacts isolated by a 150 nm deep mesa structure. The two-terminal Vbr for various Lsd at room temperature is shown in Fig. 1(b). Vbr linearly increased with increasing Lsd. The lateral two-terminal Vbr measurements likely have the high electric field applied at the mesa edge.24) The effective Ec of the UID (Al0.15Ga0.85)2O3 and Ga2O3 layers are 1.8 and 0.5 MV cm−1, respectively. These values are higher than the one typically seen in III-nitride semiconductors,25,26) showing that (AlGa)2O3 materials have high potential for high-power applications.

3.2. (AlGa)2O3/Ga2O3 MODFET

We fabricated a Sn-doped (AlGa)2O3/Ga2O3 MODFET, which consists of the 26 nm thick heavily Sn-doped (Al0.08Ga0.92)2O3/180 nm thick UID Ga2O3 structure, as schematically shown in Fig. 2(a). The net donor concentration of the (AlGa)2O3 barrier layer is estimated to be ~1018 cm−3. The fabricated MODFET had a gate length (Lg) of 2 μm, gate-source spacing (Lgs) of 2 μm, and gate-drain spacing (Lgd) of 8 μm. Figure 2(b) shows the C–V characterization at 1 MHz. The capacitance increased with increasing the voltage and exhibited the characteristic accumulation behavior near −0.5 V, indicating the presence of 2DEG. The sheet charge density n at the (AlGa)2O3/Ga2O3 interface is estimated to be 2 × 1013 cm−2 by assuming n ≈ −C3(dV/dC)/() under a homogeneously doped (AlGa)2O3 layer without compensation, where ε permittivity (10ε0 for Ga2O3) and q elementary charge.27) This n is close to the reported values of Ge-doped (Al0.08Ga0.92)2O3/Ga2O3 and Si-doped (Al0.2Ga0.8)2O3/Ga2O3 MODFETs.14,15) The depth profile of the charge concentrations in the (AlGa)2O3/Ga2O layer is inserted in Fig. 2(b). The depth w (=ε/C) is estimated from C–V measurements. The charge-peak density is located around 20 nm away from the surface. This depth is close to the (AlGa)2O3 barrier thickness, indicating the charge confinement at the (AlGa)2O3/Ga2O3 interface.

Fig. 2.

Fig. 2. (Color online) (a) Schematic cross section of Sn-doped (Al0.08Ga0.92)2O3/Ga2O3 MODFET. (b) Capacitance–voltage profile at a frequency of 1 MHz. A depth profile of the charge concentration estimated from the C–V measurements is inserted. (c) DC output characteristics of (AlGa)2O3/Ga2O3 MODFET with gate length of 2 μm at room temperature for Vgs from −2.4 to +1.2 V. (d) Transfer characteristics at a drain voltage of +10 V at room temperature.

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Figure 2(c) shows the output characteristics at room temperature for the (AlGa)2O3/Ga2O3 MODFET. The MODFET has a normally-on operation and pinch-off characteristics for gate voltage (Vgs) < −2.8 V. We achieved a fairly ohmic behavior of the source/drain contact due to the uniformly-Sn-doped (AlGa)2O3 barrier layer. The normalized Ron was measured to be 1.1 kΩ mm from a linear fit to the Vgs = 0 V curve. μe is estimated to be 8 cm2 V−1 s−1, which is slightly higher than that in the (AlGa)2O3 layer perhaps due to 2DEG formed in the UID-Ga2O3 layer. However, the estimated μe of the (AlGa)2O3/Ga2O3 MODFET is one order of magnitude lower than that of the reported Ga2O3 layers.9,23,28) The small μe may be attributed to the parallel conduction in 2DEG and the UID Ga2O3 layer. Further investigation on electrical characteristics of the (AlGa)2O3/Ga2O3 interface is necessary. Drain current (Id) is effectively modulated by Vgs and shows good saturation. The maximum Id, off-state Id, and subthreshold swing were 12 mA mm−1, 1.4 μA mm−1 and 0.4 V decade−1, respectively, as shown in Fig. 2(d). The high off-state Id may result from the leakage current through the Ga2O3 buffer/substrate interface with the unintentional Si incorporation.20) The maximum transconductance (gm) and Id on/off ratio were 3.8 mS mm−1 and 8.7 × 103, respectively. The three-terminal Vbr for Vgs = −10 V at room temperature was 610 V, which is higher than that of 415 V for the reported lateral Ga2O3 MOSFET.21)

3.3. (AlGa)2O3-channel MESFET

To investigate the lateral Ec of (AlGa)2O3 layers, we prepared Sn-doped (AlGa)2O3-channel MESFETs made of a 120 nm thick Sn-doped (Al0.16Ga0.84)2O3 channel with the donor concentration of ~1017 cm−3 on a 120 nm thick UID (Al0.16Ga0.84)2O3 buffer, as schematically shown in Fig. 3(a). The transistors featured a 70 nm deep gate recess. Output characteristics at room temperature for the MESFET are shown in Fig. 3(b). The MESFETs have a nearly normally-off operation with pinch-off characteristics for Vgs < −0.4 V due to the light Sn-doping and gate recess structure. The subthreshold swing was 0.3 V decade−1. In these devices, Id is effectively modulated by Vgs and shows good saturation. The transfer characteristics of the MESFET with Lgd of 4 μm at a drain voltage (Vds) = +4 V at room temperature is shown in Fig. 3(c). At room temperature, the off-state Id was 0.6 nA mm−1, which is comparable with the gate current, indicating a negligibly-small leakage current through the UID (AlGa)2O3 layers. The maximum transconductance was 1.6 μS mm−1. The maximum Id was 3.3 μA mm−1 for Vgs = +1.0 V. The low Id is attributed to the deep gate recess and high contact resistance. The Id on/off ratio was around 103. Regrowth of a n++-(AlGa)2O3 contact layer or Si-ion implantation under source/drain electrodes would further increase the Id on/off ratio.

Fig. 3.

Fig. 3. (Color online) (a) Schematic cross section of Sn-doped (Al0.16Ga0.84)2O3/(Al0.16Ga0.84)2O3 MESFET. (b) DC output characteristics of lightly Sn-doped (Al0.16Ga0.84)2O3 MESFET with gate length of 2 μm at room temperature for Vgs from 0 to +1 V. (c) Transfer characteristics at a drain voltage of +4 V at room temperature. (d) Three-terminal off-state breakdown voltage as a function of gate-to-drain spacing. Off-state breakdown characteristics of (AlGa)2O3 MESFET with drain-to-gate spacing of 20 μm at a gate voltage of −10 V at room temperature is inserted.

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The three-terminal Vbr characteristics for the (AlGa)2O3 MESFET with Lgd of 20 μm at room temperature is inserted in Fig. 3(d). The leakage current of off-state Id was below 1 nA mm−1 at −600 V. Vbr for Vgs = −10 V at room temperature was 940 V, indicating the high potential of (AlGa)2O3 for high-power applications. The three-terminal Vbr for various Lgd at room temperature are shown in Fig. 3(d). Vbr increases linearly with increasing Lgd. This is because the device breakdown is mainly caused by the high electric field at the drain edge of the gate electrode, resulting in the lower effective Ec in comparison with the two-terminal Vbr measurement for (AlGa)2O3. The effective lateral Ec of the three-terminal Vbr for (AlGa)2O3 is 0.6 MV cm−1, which is comparable to GaN HEMTs.29,30) Further high breakdown voltages of the MODFETs and MESFETs are expected in devices with a field-plate structure.

4. Conclusions

We report on the electrical characteristics of different (AlGa)2O3 layers. The Sn-doped (Al0.15Ga0.85)2O3 layer exhibits a fairly ohmic behavior, showing a contact resistance of 9 × 10−5 Ω cm2 and a sheet resistance of 75 kΩ/squ. The effective critical electrical field of the (Al0.15Ga0.85)2O3 layer is 1.8 MV cm−1. Additionally, we demonstrated (AlGa)2O3-based MODFETs and MESFETs. The (Al0.08Ga0.92)2O3/Ga2O3 MODFET has a maximum drain current of 12 mA mm−1 for a gate voltage of +3 V and an on/off current ratio of ~104 at room temperature. The three-terminal off-state breakdown voltage of the (Al0.16Ga0.84)2O3-channel MESFETs is 940 V for drain-to-gate spacing of 20 μm. The (AlGa)2O3-used transistors show great potential for high-power applications.

Acknowledgments

This work was supported by JSPS KAKENHI Grant No. 16H06424 and 16K13673, and the DARPA DREaM program, monitored by Dr. Young-Kai Chen and Dr. Paul Maki. This work was carried out in part through the use of MIT's Microsystems Technology Laboratories.

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10.7567/1347-4065/ab002b