Fluctuation-dissipation theorem in nonequilibrium steady states

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Published 21 January 2010 Europhysics Letters Association
, , Citation U. Seifert and T. Speck 2010 EPL 89 10007 DOI 10.1209/0295-5075/89/10007

0295-5075/89/1/10007

Abstract

In equilibrium, the fluctuation-dissipation theorem (FDT) expresses the response of an observable to a small perturbation by a correlation function of this variable with another one that is conjugate to the perturbation with respect to energy. For a nonequilibrium steady state (NESS), the corresponding FDT is shown to involve in the correlation function a variable that is conjugate with respect to entropy. By splitting up entropy production into one of the system and one of the medium, it is shown that for systems with a genuine equilibrium state the FDT of the NESS differs from its equilibrium form by an additive term involving total entropy production. A related variant of the FDT not requiring explicit knowledge of the stationary state is particularly useful for coupled Langevin systems. The a priori surprising freedom apparently involved in different forms of the FDT in a NESS is clarified.

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