Recent Developments of Semi-fuel Cells for Powering Underwater Sensors and Platforms

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© 2010 ECS - The Electrochemical Society
, , Citation Andres M. Cardenas-Valencia et al 2010 ECS Trans. 26 417 DOI 10.1149/1.3429015

1938-5862/26/1/417

Abstract

This paper studies two novel galvanic cells and postulates their use in underwater power applications. One couples Aluminum to sodium peroxide (Al-Na2O2) and the other to a chlorinated halamine (Al-C3N3Cl3O3). Experimental results show that the chemistries are indeed capable of providing good specific energies. The results from small cells showed an specific energy (SE) of 200 Wh/kg, (~ 300 Wh/kg, if the packaging is not considered) for the Al-halamine cell. The SE of Al-alkali perox¬ide was found to be approximately 230 Wh/kg (460 Wh/kg, considering only active materials). Interestingly, latest results indicate that it is possible to increase the current of a given cell by using high surface area electrodes. Results using high surface area, porous, foam-like materials are estimated and show promising results their use in semi-fuel cell schemes (SE on the order of 0.5 kWh/Kg).

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10.1149/1.3429015