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Effect of Cerium Doping on Morphology and Physical Properties of α-Fe2O3 Films Prepared by Hydrothermal Electrodeposition

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© 2014 ECS - The Electrochemical Society
, , Citation Ceren Yilmaz and Ugur Unal 2014 ECS Trans. 58 55 DOI 10.1149/05819.0055ecst

1938-5862/58/19/55

Abstract

In this study, electrochemical growth of Ce-doped α-Fe2O3 films is reported. Electrodeposition at 75°C and also a combined hydrothermal-electrochemical method to obtain hematite are presented. Both acidic and neutral plating solutions were used for the depositions. Ferric oxyhydroxide is produced by electrodeposition at 75°C and converted to hematite phase after annealing. Hydrothermal-electrodeposition at 130°C results in formation of hematite phase directly. The effect of temperature, deposition solution and cerium ion amount on the morphology and physical properties of hematite films are characterized.

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10.1149/05819.0055ecst