Superstructure in Thin Films of Bi-Based Compounds on MgO

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Copyright (c) 1990 The Japan Society of Applied Physics
, , Citation Kazuyoshi Kojima et al 1990 Jpn. J. Appl. Phys. 29 L1638 DOI 10.1143/JJAP.29.L1638

1347-4065/29/9A/L1638

Abstract

In situ epitaxial growth of BiSrCaCuO films by three target sputtering was performed on MgO substrates at a temperature of 650°C. From high resolution transmission electron microscopy, the film showed a superstructure consisting of the alternate stacking of the low-Tc and high-Tc phases with a c-axis of 34 Å. The film in the [110] or [1 bar 10] directions was parallel to <100 >MgO, and the transient layers between the substrate and the film were less than a few atomic layers thick. X-ray diffraction simulations indicated that the films contained random layer ordering of 34 Å bi-layers (low-Tc+high-Tc and high-Tc+low-Tc) and random layer ordering of low-Tc and high-Tc phase layers.

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10.1143/JJAP.29.L1638