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Paper The following article is Open access

Non-oxidative methane conversion over Mo/ZSM-5 catalysts with mesoporous structure

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Published under licence by IOP Publishing Ltd
, , Citation A V Vosmerikov et al 2019 IOP Conf. Ser.: Mater. Sci. Eng. 597 012019 DOI 10.1088/1757-899X/597/1/012019

1757-899X/597/1/012019

Abstract

Physicochemical and catalytic properties of 4.0% Mo/ZSM-5 catalysts manufactured on the basis of zeolites with a hierarchical pore system are investigated. The effect of the conditions of synthesis of zeolites with an additional mesoporous structure on their textural and acidic characteristics is studied. The structure and morphology of crystals of synthesized zeolites and catalysts produced from them are determined by the methods of X-ray diffraction analysis and high-resolution scanning transmission electron microscopy. It is shown that 4.0% Mo/ZSM-5 catalysts produced from zeolites with a mesoporous structure exhibit higher activity and stability in the course of methane dehydroaromatization.

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10.1088/1757-899X/597/1/012019