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Aggregation study in mixture surfactant system TX-100+SDS in heavy water solutions by SANS method

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, , Citation A. Rajewska et al 2018 J. Phys.: Conf. Ser. 994 012015 DOI 10.1088/1742-6596/994/1/012015

1742-6596/994/1/012015

Abstract

The mixing of amphiphiles in water may lead to the formation of mixed micelles which often present new properties with respect to the pure component solutions [1,2]. The mixture system of classic surfactants SDS (sodium dodecyl sulfate)+TX-100(p-(1,1,3,3- tetramethyl) poly(oxyethylene) (anionic + non-ionic) in heavy water solutions was investigated at temperatures 30°, 50°, 70°C for compositions 1:1, 2:1, 3:1 by the small-angle neutron scattering(SANS) method on spectrometer ('YuMO') at the IBR-2 pulsed neutron source at FLNP, JINR in Dubna (Russia). Measurements have covered Q range from 8x10-3 to 0.4 Å-1. From the measured dependence of the scattered intensity on the scattering angle, we derived the size, shape of micelles, aggregation number at various compositions and temperatures. The size of mixed micelle is a weak function of the mixing ratio between the two components.

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10.1088/1742-6596/994/1/012015