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Paper The following article is Open access

Design and compressibility of Langmuir monolayers from organometallic nanocyclic complexes

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Published under licence by IOP Publishing Ltd
, , Citation H V Grushevskaya et al 2016 J. Phys.: Conf. Ser. 741 012116 DOI 10.1088/1742-6596/741/1/012116

1742-6596/741/1/012116

Abstract

We propose to control design of organometallic conducting Langmuir monolayer by utilizing geometrodynamic approach. By means of this approach the compressibility of the monolayer, which consists of molecules of thiophene-pyrrole series oligomer with covalently bound hydrophobic alkyl chain, has been analyzed for different subphase with iron salts. It has been discovered that the monolayers are polymerized and turn into monolayers of nanocyclic organometallic coordination compounds at a two-dimensional phase transition of the first order.

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10.1088/1742-6596/741/1/012116