Abstract
TiAlN/VN multilayer coatings exhibit excellent dry sliding wear resistance and low friction coefficient, believed to be associated with the formation of tribo-films comprising Magnéli phases such as V2O5. In order to investigate this hypothesis, dry sliding wear of TiAlN/VN coatings was undertaken against Al2O3. Focused ion beam was used to generate site-specific TEM specimens. A thin (2-20nm) tribo-film was observed at the worn surface, with occasional 'roll-like' wear debris (ϕ 5-40nm). Both were amorphous and contained the same Ti, Al and V ratio as the coating, but with the nitrogen largely replaced by oxygen. No evidence of Magnéli phases was found.
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