Abstract
Quartz is a variety of gemstone consisting of SiO2. The various colors of quartz are caused by Fe as a trace element. This study focused on the investigation of Fe oxidation states affecting colorations of purple- and yellow- quartz by X-ray absorption spectroscopy (XAS) and UV-Vis-NIR spectroscopy. The amethyst (purple- quartz) and citrine (yellow- quartz) were collected as the samples. As the XAS results, there was only Fe3+ oxidation state on both purple-and yellow- quartz considering with the absorption energy position at the Fe K-edge compared to the Fe-oxide chemical standards i.e., FeO and Fe2O3. However, the UV-Vis-NIR absorption spectra of the purple- and yellow- quartz were different. Therefore, we propose that the coloration of purple- and yellow- quartz was caused by Fe3+ oxidation states as the donor states at 3.59 eV and 2.28 eV with the different energy band gaps of the purple- and yellow- quartz that were 4.13 eV and 4.88 eV respectively derived from Tauc Plot method.
Export citation and abstract BibTeX RIS
Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.