Abstract
The theory of ferromagnetism is often developed on the assumption that the exchange energy responsible for the magnetization is adequately represented as a sum of exchange integrals between pairs of electrons with mutually parallel spins. This is equivalent to using for the total wave function a determinant built up of one-electron functions. For the magnetized states of interest in ferromagnetism a single determinant wave function must be regarded as inadequate on account of the so-called spin or exchange degeneracy, which requires us to use instead appropriate linear combinations of the degenerate determinants. In the present paper a model is presented for which the results of neglecting or taking account of this spin degeneracy are identical. The model can be handled exactly and leads to equations for the free energy, magnetization, etc., which are a generalization of Stoner's theory of ferromagnetism to a system with two energy bands; these could be the overlapping 3d and 4s bands in the iron transition series. The calculations are not necessarily restricted to ferromagnetic metals and would apply equally well to those that are paramagnetic.