Inequality for the specific heat: I. Derivation

Published under licence by IOP Publishing Ltd
, , Citation B D Josephson 1967 Proc. Phys. Soc. 92 269 DOI 10.1088/0370-1328/92/2/301

0370-1328/92/2/269

Abstract

A rigorous inequality is derived relating the specific heat of a system, the temperature derivative of the expectation value of an arbitrary operator and the mean-square fluctuation of the operator in an equilibrium ensemble. The class of constraints for which the theorem is shown to hold includes most of those of practical interest, in particular the constancy of the volume, the pressure, and (where applicable) the magnetization and the applied magnetic field.

Export citation and abstract BibTeX RIS

10.1088/0370-1328/92/2/301