Keywords

We study the effect of adsorption of volatile organic compounds (VOCs) in Enceladus' geysers, both onto the ice grains ejected in the plumes, and onto the ice walls of the cracks connecting Enceladus' internal ocean to its surface. We use a model of adsorption/desorption based on the Polanyi–Wiegner equation and experimental values of binding energies (energy of desorption E_des) of the adsorbed compounds to water ice. We find that under conditions expected at Enceladus, the process of adsorption tends to ensure that the VOCs with the highest binding energy are over-represented on the ice surface, even if their abundance is comparatively lower than those of other compounds. We find that VOCs with E_des ≤ 0.5 eV are insignificantly affected by adsorption while compounds with E_des ≥ 0.7 eV are readily retained on the surface and compete to occupy most of the adsorption sites. We also deduce that ice grains falling back onto the surface are likely to retain most of the molecules adsorbed on their surface. The implication is that remote observation or sampling of the ice in the cracks or of the surface around it would show a mixture of VOCs that would not be representative of the gas phase of the plumes, with the high E_des VOCs dominating the adsorbed phase.

We apply histogram analysis, photogeological methods, and tidal stress modeling to Porco et al.'s survey of 101 Enceladus South Polar Basin geysers and their three-dimensional orientations to test if the jet azimuths are influenced by their placement relative to surface morphology and tectonic structures. Geysers emplaced along the three most active tiger stripe fractures (Damascus Sulcus, Baghdad Sulcus, and Cairo Sulcus) occur in local groupings with relatively uniform nearest-neighbor separation distances (∼5 km). Their placement may be controlled by uniformly spaced en echelon Riedel-type shear cracks originating from left-lateral strike-slip fault motion inferred to occur along tiger stripes. The spacing would imply a lithosphere thickness of ∼5 km in the vicinity of the tiger stripes. The orientations of tilted geyser jets are not randomly distributed; rather their azimuths correlate with the directions either of tiger stripes, cross-cutting fractures, or else fine-scale local tectonic fabrics. Diurnal tidal stress modeling suggests that periodic changes of plume activity are significantly affected by cross-cutting fractures that open and close at different times than the tiger stripes that they intersect. We find evidence of sub-kilometer scale morphological modification of surface geological features surrounding geysers from sublimation-aided erosion, and ablation, and scouring. We propose that the simultaneous crushing and shearing action of periodic transpressional tidal stress on ice condensing on the inside walls of geyser conduits is the mechanism that extrudes the peculiar, paired narrow ridges known as "shark fins" that flank the medial tiger stripe fissures. We present a gallery of high-resolution image mosaics showing the placement of all the jets in their source region and consequently their geological context.

We present the first comprehensive examination of the geysering, tidal stresses, and anomalous thermal emission across the south pole of Enceladus and discuss the implications for the moon's thermal history and interior structure. A 6.5 yr survey of the moon's south polar terrain (SPT) by the Cassini imaging experiment has located ∼100 jets or geysers erupting from four prominent fractures crossing the region. Comparing these results with predictions of diurnally varying tidal stresses and with Cassini low resolution thermal maps shows that all three phenomena are spatially correlated. The coincidence of individual jets with very small (∼10 m) hot spots detected in high resolution Cassini VIMS data strongly suggests that the heat accompanying the geysers is not produced by shearing in the upper brittle layer but rather is transported, in the form of latent heat, from a sub-ice-shell sea of liquid water, with vapor condensing on the near-surface walls of the fractures. Normal stresses modulate the geysering activity, as shown in the accompanying paper; we demonstrate here they are capable of opening water-filled cracks all the way down to the sea. If Enceladus' eccentricity and heat production are in steady state today, the currently erupting material and anomalous heat must have been produced in an earlier epoch. If regional tidal heating is occurring today, it may be responsible for some of the erupting water and heat. Future Cassini observations may settle the question.

We use images acquired by the Cassini Imaging Science Subsystem (ISS) to investigate the temporal variation of the brightness and height of the south polar plume of Enceladus. The plume's brightness peaks around the moon's apoapse, but with no systematic variation in scale height with either plume brightness or Enceladus' orbital position. We compare our results, both alone and supplemented with Cassini near-infrared observations, with predictions obtained from models in which tidal stresses are the principal control of the eruptive behavior. There are three main ways of explaining the observations: (1) the activity is controlled by right-lateral strike slip motion; (2) the activity is driven by eccentricity tides with an apparent time delay of about 5 hr; (3) the activity is driven by eccentricity tides plus a 1:1 physical libration with an amplitude of about 08 (3.5 km). The second hypothesis might imply either a delayed eruptive response, or a dissipative, viscoelastic interior. The third hypothesis requires a libration amplitude an order of magnitude larger than predicted for a solid Enceladus. While we cannot currently exclude any of these hypotheses, the third, which is plausible for an Enceladus with a subsurface ocean, is testable by using repeat imaging of the moon's surface. A dissipative interior suggests that a regional background heat source should be detectable. The lack of a systematic variation in plume scale height, despite the large variations in plume brightness, is plausibly the result of supersonic flow; the details of the eruption process are yet to be understood.

We describe a formation scenario of Enceladus constrained by the deuterium-to-hydrogen ratio (D/H) in the gas plumes as measured by the Cassini Ion and Neutral Mass Spectrometer. We propose that, similarly to Titan, Enceladus formed from icy planetesimals that were partly devolatilized during their migration within the Kronian subnebula. In our scenario, at least primordial Ar, CO, and N₂ were devolatilized from planetesimals during their drift within the subnebula, due to the increasing temperature and pressure conditions of the gas phase. The origin of methane is still uncertain since it might have been either trapped in the planetesimals of Enceladus during their formation in the solar nebula or produced via serpentinization reactions in the satellite's interior. If the methane of Enceladus originates from the solar nebula, then its D/H ratio should range between ∼4.7 × 10⁻⁵ and 1.5 × 10⁻⁴. Moreover, Xe/H₂O and Kr/H₂O ratios are predicted to be equal to ∼7 × 10⁻⁷ and 7 × 10⁻⁶, respectively, in the satellite's interior. On the other hand, if the methane of Enceladus results from serpentinization reactions, then its D/H ratio should range between ∼2.1 × 10⁻⁴ and 4.5 × 10⁻⁴. In this case, Kr/H₂O should not exceed ∼10⁻¹⁰ and Xe/H₂O should range between ∼1 × 10⁻⁷ and 7 × 10⁻⁷ in the satellite's interior. Future spacecraft missions, such as Titan Saturn System Mission, will have the capability to provide new insight into the origin of Enceladus by testing these observational predictions.