For the case of the bipolaron, it has been proved recently that for U ⩾ 53.2α, where U is the repulsion parameter of the electrons and α is the coupling constant of the polaron, no binding occurs. We show that actually for U ⩾ 52.1α, there is no binding. Furthermore, we obtain optimized results for small and large values of α: more specifically, we prove that for each ε > 0, there is an α1 and an α2, such that if 0 < α ⩽ α1, a condition for no-binding becomes U ⩾ (40.4 + ε)α, and if α ⩾ α2, it is U ⩾ (38.7 + ε)α. We show that α1 can be computed with any desired accuracy, whereas we are merely able to prove the existence of such an α2.