Table of contents

Semiconducting two-dimensional (2D) materials, particularly extremely thin molybdenum disulfide (MoS₂) films, are attracting considerable attention from academia and industry owing to their distinctive optical and electrical properties. Here, we present the direct growth of a MoS₂ monolayer with unprecedented spatial and structural uniformity across an entire 8 inch SiO₂/Si wafer. The influences of growth pressure, ambient gases (Ar, H₂), and S/Mo molar flow ratio on the MoS₂ layered growth were explored by considering the domain size, nucleation sites, morphology, and impurity incorporation. Monolayer MoS₂-based field effect transistors achieve an electron mobility of 0.47 cm² V⁻¹ s⁻¹ and on/off current ratio of 5.4 × 10⁴. This work demonstrates the potential for reliable wafer-scale production of 2D MoS₂ for practical applications in next-generation electronic and optical devices.

In this paper, we investigate the recovery of some semiconductor-based components, such as N/P-type field-effect transistors (FETs) and a complementary metal–oxide–semiconductor (CMOS) inverter, after being exposed to a high total dose of gamma ray radiation. The employed method consists mainly of a rapid, low power and in situ annealing mitigation technique by silicon-on-insulator micro-hotplates. Due to the ionizing effect of the gamma irradiation, the threshold voltages showed an average shift of −580 mV for N-channel transistors, and −360 mV for P-MOSFETs. A 4 min double-cycle annealing of components with a heater temperature up to 465 °C, corresponding to a maximum power of 38 mW, ensured partial recovery but was not sufficient for full recovery. The degradation was completely recovered after the use of a built-in high temperature annealing process, up to 975 °C for 8 min corresponding to a maximum power of 112 mW, which restored the normal operating characteristics for all devices after their irradiation.

We describe the super compressible and highly recoverable response of bucky sponges as they are struck by a heavy flat-punch striker. The bucky sponges studied here are structurally stable, self-assembled mixtures of multiwalled carbon nanotubes (MWCNTs) and carbon fibers (CFs). We engineered the microstructure of the sponges by controlling their porosity using different CF contents. Their mechanical properties and energy dissipation characteristics during impact loading are presented as a function of their composition. The inclusion of CFs improves the impact force damping by up to 50% and the specific damping capacity by up to 7% compared to bucky sponges without CFs. The sponges also exhibit significantly better stress mitigation characteristics compared to vertically aligned CNT foams of similar densities. We show that delamination occurs at the MWCNT–CF interfaces during unloading, and it arises from the heterogeneous fibrous microstructure of the bucky sponges.

Graphene membranes have the potential to exceed the permeance and selectivity limits of conventional gas separation membranes. Realizing this potential in practical systems relies on overcoming numerous scalability challenges, such as isolating or sealing permeable defects in macroscopic areas of graphene that can compromise performance and developing methods to create high densities of selective pores over large areas. This study focuses on a centimeter-scale membrane design, where leakage is reduced by substrate selection, permeable polymer film coating, and stacking of three independent layers of graphene, while (selective) pores are created by high density ion bombardment. The three-layer graphene provides high resistance to gas flow, which decreases with ion bombardment and results in selectivity consistent with Knudsen effusion. The results suggest that the permeable pores created in three layer graphene were larger than those required for molecular sieving and that designs based on single layer graphene may lend themselves more easily to molecular sieving of gases.

This work presents the synthesis by coprecipitation of diamond shaped Yb:Er:NaGd(WO₄)₂ crystalline nanoparticles (NPs) with diagonal dimensions in the 5–7 nm × 10–12 nm range which have been modified with TWEEN80 for their dispersion in water, and their interaction with mesenchymal stem cells (MSCs) proposed as cellular NP vehicles. These NPs belong to a large family of tetragonal Yb:Er:NaT(XO₄)₂ (T = Y, La, Gd, Lu; X = Mo, W) compounds with green (²H_11/2 + ⁴S_3/2 → ⁴I_15/2) Er-related upconversion (UC) efficiency comparable to that of Yb:Er:β-NaYF₄ reference compound, but with a ratiometric thermal sensitivity (S) 2.5–3.5 times larger than that of the fluoride. At the temperature range of interest for biomedical applications (∼293–317 K/20–44 °C) S = 108–118 × 10⁻⁴ K⁻¹ for 20 at%Yb:5 at%Er:NaGd(WO₄)₂ NPs, being the largest values so far reported using the ²H_11/2/⁴S_3/2 Er intensity ratiometric method. Cultured MSCs, incubated with these water NP emulsions, internalize and accumulate the NPs enclosed in endosomes/lysosomes. Incubations with up to 10 μg of NPs per ml of culture medium maintain cellular metabolism at 72 h. A thermal assisted excitation path is discussed as responsible for the UC behavior of Yb:Er:NaT(XO₄)₂ compounds.

Here we report indocyanine green (ICG)-loaded hollow mesoporous silica nanoparticles (ICG@HMSNP) as an activatable theranostic platform. Near-infrared fluorescence and singlet oxygen generation of ICG@HMSNP was effectively quenched (i.e. turned off) in its native state because of the fluorescence resonance energy transfer between ICG molecules. Therefore, ICG@HMSNP was nonfluorescent and nonphototoxic in the extracellular region. After the nanoparticles entered the cancer cells via endocytosis, they became highly fluorescent and phototoxic. In addition, intracellular uptake of ICG@HMSNP was 2.75 times higher than that of free ICG, resulting in an enhanced phototherapy of cancer.

Overcoming the diffraction limit to achieve high optical resolution is one of the main challenges in the fields of plasmonics, nanooptics and nanophotonics. In this work, we introduce novel plasmonic structures consisting of nanoantennas (nanoprisms, single bowtie nanoantennas and double bowtie nanoantennas) integrated in the center of ring diffraction gratings. Propagating surface plasmon polaritons (SPPs) are generated by the ring grating and coupled with localized surface plasmons (LSPs) at the nanoantennas exciting emitters placed in their gap. SPPs are widely used for optical waveguiding but provide low resolution due to their weak spatial confinement. In contrast, LSPs provide excellent sub-wavelength confinement but induce large losses. The phenomenon of SPP–LSP coupling witnessed in our structures allows for achieving more precise focusing at the nanoscale, causing an increase in the fluorescence emission of the emitters. Finite-difference time-domain simulations as well as experimental fabrication and optical characterization results are presented to study plasmon–emitter coupling between an ensemble of dye molecules and our integrated plasmonic structures. A comparison is given to highlight the importance of each structure on the photoluminescence and radiative decay enhancement of the molecules.

We compare classical versus quantum electron transport in recently investigated magnetic focusing devices (Bhandari et al 2016 Nano Lett.16 1690) exposed to the perturbing potential of a scanning gate microscope (SGM). Using the Landauer–Büttiker formalism for a multi-terminal device, we calculate resistance maps that are obtained as the SGM tip is scanned over the sample. There are three unique regimes in which the scanning tip can operate (focusing, repelling, and mixed regime) which are investigated. Tip interacts mostly with electrons with cyclotron trajectories passing directly underneath it, leaving a trail of modified current density behind it. Other (indirect) trajectories become relevant when the tip is placed near the edges of the sample, and current is scattered between the tip and the edge. We point out that, in contrast to SGM experiments on gapped semiconductors, the STM tip can induce a pn junction in graphene, which improves contrast and resolution in SGM. We also discuss possible explanations for spatial asymmetry of experimentally measured resistance maps, and connect it with specific configurations of the measuring probes.

The plasmonic cavity arrays are ideal substrates for surface enhanced Raman scattering analysis because they can provide hot spots with large volume for analyte molecules. The large area increases the probability to make more analyte molecules on hot spots and leads to a high reproducibility. Therefore, to develop a simple method for creating cavity arrays is important. Herein, we demonstrate how to fabricate a V and W shape cavity arrays by a simple method based on self-assembly. Briefly, the V and W shape cavity arrays are respectively fabricated by taking KOH etching on a nanohole and a nanoring array patterned silicon (Si) slides. The nanohole array is generated by taking a reactive ion etching on a Si slide assembled with monolayer of polystyrene (PS) spheres. The nanoring array is generated by taking a reactive ion etching on a Si slide covered with a monolayer of octadecyltrichlorosilane before self-assembling PS spheres. Both plasmonic V and W cavity arrays can provide large hot area, which increases the probability for analyte molecules to deposit on the hot spots. Taking 4-Mercaptopyridine as analyte probe, the enhancement factor can reach 2.99 × 10⁵ and 9.97 × 10⁵ for plasmonic V cavity and W cavity array, respectively. The relative standard deviations of the plasmonic V and W cavity arrays are 6.5% and 10.2% respectively according to the spectra collected on 20 random spots.

Large over-potentials during battery operation remain a big obstacle for aprotic Li–O₂ batteries. Herein, a nanocomposite of about 4 nm cobalt monoxide nanocrystals grown in situ on reduced graphene oxide substrates (CoO/RGO) has been synthesized via a thermal decomposition method. The CoO/RGO cathode delivers a high initial capacity of 14 450 mAh g⁻¹ at a current density of 200 mA g⁻¹. Simultaneously it displays little capacity fading after 32 cycles with a capacity restriction of 1000 mAh g⁻¹. Additionally, compared with Ketjenblack and general CoO nanoparticles, ultrathin CoO nanoparticle-decorated RGO electrode materials with a delaminated structure display an observable reduction of over-potential in Li–O₂ batteries. These results demonstrate that the introduction of RGO improves the performance of CoO, which is a promising strategy for optimizing the design of electrocatalysts for aprotic rechargeable Li–O₂ batteries.

A low filling ratio and enhanced absorption is needed to enable the full potential of Si nanowire (NW) arrays for optoelectronic applications. In this paper, we report a versatile, scalable fabrication technique that uses nanosphere lithography (NSL) patterning for the synthesis of vertically aligned Si and Si/SiO₂ NW arrays. The optical reflection of the NW arrays can be substantially suppressed by the addition of the transparent shell. Meanwhile, by the finite-difference time-domain (FDTD) simulation, we find that the absorption enhancement in the core Si NW can be obtained by adding the transparent shell. The special absorption enhancement of the Si NW arrays with a core–shell structure can be theoretically understood by modal analysis. The absorption in such Si NW array structures is very sensitive to the thickness of transparent coating. By the addition of a SiO₂ shell layer, the absorption in the inner Si NW array can be substantially enhanced. Furthermore, significant absorption enhancement and broadband anti-reflection effects can be achieved by the diluted Si NWs combined with the single dielectric shell.

Ocean waves are one of the cleanest and most abundant energy sources on earth, and wave energy has the potential for future power generation. Triboelectric nanogenerator (TENG) technology has recently been proposed as a promising technology to harvest wave energy. In this paper, a theoretical study is performed on a duck-shaped TENG wave harvester recently introduced in our work. To enhance the design of the duck-shaped TENG wave harvester, the mechanical and electrical characteristics of the harvester's overall structure, as well as its inner configuration, are analyzed, respectively, under different wave conditions, to optimize parameters such as duck radius and mass. Furthermore, a comprehensive hybrid 3D model is introduced to quantify the performance of the TENG wave harvester. Finally, the influence of different TENG parameters is validated by comparing the performance of several existing TENG wave harvesters. This study can be applied as a guideline for enhancing the performance of TENG wave energy harvesters.

The chemical vapor deposition (CVD) growth of graphene on copper is controlled by a complex interplay of substrate preparation, substrate temperature, pressure and flow of reactive gases. A large variety of recipes have been suggested in literature, often quite specific to the reactor, which is being used. Here, we report on a relation between growth rate and quality of graphene grown in a scalable 4'' CVD reactor. The growth rate is varied by substrate pre-treatment, chamber pressure, and methane to hydrogen (CH₄:H₂) ratio, respectively. We found that at lower growth rates graphene grains become hexagonal rather than randomly shaped, which leads to a reduced defect density and a sheet resistance down to 268 Ω/sq.

Hexagonal boron nitride (h-BN) nanowalls (BNNWs) were synthesized by plasma-enhanced chemical vapor deposition (PECVD) from a borazine (B₃N₃H₆) and ammonia (NH₃) gas mixture at a low temperature range of 400 °C–600 °C on GaAs(100) substrates. The effect of the synthesis temperature on the structure and surface morphology of h-BN films was investigated. The length and thickness of the h-BN nanowalls were in the ranges of 50–200 nm and 15–30 nm, respectively. Transmission electron microscope images showed the obtained BNNWs were composed of layered non-equiaxed h-BN nanocrystallites 5–10 nm in size. The parallel-aligned h-BN layers as an interfacial layer were observed between the film and GaAs(100) substrate. BNNWs demonstrate strong blue light emission, high transparency (>90%) both in visible and infrared spectral regions and are promising for optical applications. The present results enable a convenient growth of BNNWs at low temperatures.

We present facile synthesis of bright CdS/CdSe/CdS@SiO₂ nanoparticles with 72% of quantum yields (QYs) retaining ca 80% of the original QYs. The main innovative point is the utilization of the highly luminescent CdS/CdSe/CdS seed/spherical quantum well/shell (SQW) as silica coating seeds. The significance of inorganic semiconductor shell passivation and structure design of quantum dots (QDs) for obtaining bright QD@SiO₂ is demonstrated by applying silica encapsulation via reverse microemulsion method to three kinds of QDs with different structure: CdSe core and 2 nm CdS shell (CdSe/CdS-thin); CdSe core and 6 nm CdS shell (CdSe/CdS-thick); and CdS core, CdSe intermediate shell and 5 nm CdS outer shell (CdS/CdSe/CdS-SQW). Silica encapsulation inevitably results in lower photoluminescence quantum yield (PL QY) than pristine QDs due to formation of surface defects. However, the retaining ratio of pristine QY is different in the three silica coated samples; for example, CdSe/CdS-thin/SiO₂ shows the lowest retaining ratio (36%) while the retaining ratio of pristine PL QY in CdSe/CdS-thick/SiO₂ and SQW/SiO₂ is over 80% and SQW/SiO₂ shows the highest resulting PL QY. Thick outermost CdS shell isolates the excitons from the defects at surface, making PL QY relatively insensitive to silica encapsulation. The bright SiO₂-coated SQW sample shows robustness against harsh conditions, such as acid etching and thermal annealing. The high luminescence and long-term stability highlights the potential of using the SQW/SiO₂ nanoparticles in bio-labeling or display applications.

Porous and photoelectrochemically active Fe-doped WO₃ nanostructures were obtained by a combinatorial dealloying method. Two types of precursor materials libraries, exhibiting dense and nano-columnar morphology were fabricated by using two distinct magnetron sputter deposition geometries. Both libraries were subjected to combinatorial dealloying enabling preparation and screening of a large quantity of compositions having different nanostructures. This approach allows identifying materials with interesting photoelectrochemical characteristics. The dealloying process selectively dissolved Fe from the composition gradient precursor W–Fe materials library, resulting in formation of monoclinic single crystalline nanoblade-like structures over the entire surface. Photoelectrochemical properties of nanostructured Fe:WO₃ films were found to be composition-dependent. The measurement region doped with ∼1.7 at % Fe and a film thickness of ∼ 900–1100 nm displayed highly porous WO₃ nanostructures and exhibited the highest photocurrent density of ∼ 72 μA cm⁻². This enhanced photocurrent density is attributed to the decreased bandgap values, suppressed recombination of electron–hole pairs, improved light absorption as well as efficient charge transport in the highly porous Fe-doped film with single crystalline WO₃ nanoblades.

The thermal transport properties of random network, single-walled carbon nanotube (SWNT) films were assessed using Raman spectroscopy. Two types of SWNT films were investigated: single-layer and stacked. The single-layer films were fabricated by aerosol chemical vapour deposition and subsequent direct dry deposition, while the stacked films were prepared by placing the single-layer films on top of one another. The anisotropy of the network structures of each of these films was evaluated based on the angular dependence of the optical absorbance spectra. The results show that the anisotropy of the films decreases with increasing film thickness in the case of the single-layer films, and that the film anisotropy is preserved during the stacking process. The sheet thermal conductance is proportional to the SWNT area density in the case of stacked films, but is reduced with increasing thickness in the case of single-layer films. This effect is explained by a change in the network morphology from a two-dimensional anisotropic structure to the more isotropic structure. This work demonstrates the fabrication of low-density films with high sheet thermal conductance through the stacking of thin SWNT films.

Organic/inorganic hybrid structures have been widely studied because of their enhanced physical and chemical properties. Monolayers of transition metal dichalcogenides (1L-TMDs) and organic nanoparticles can provide a hybridization configuration between zero- and two-dimensional systems with the advantages of convenient preparation and strong interface interaction. Here, we present such a hybrid system made by dispersing π-conjugated organic (tris (8-hydroxyquinoline) aluminum(III)) (Alq₃) nanoparticles (NPs) on 1L-MoS₂. Hybrids of Alq₃ NP/1L-MoS₂ exhibited a two-fold increase in the photoluminescence of Alq₃ NPs on 1L-MoS₂ and the n-doping effect of 1L-MoS₂, and these spectral and electronic modifications were attributed to the charge transfer between Alq₃ NPs and 1L-MoS₂. Our results suggested that a hybrid of organic NPs/1L-TMD can offer a convenient platform to study the interface interactions between organic and inorganic nano objects and to engineer optoelectronic devices with enhanced performance.

Since porous anodic alumina (PAA) is a frequently-used optical waveguide material, accurate characterization of its structure parameters and optical properties is in urgent need. To characterize PAA, spectroscopic ellipsometry is preferred due to its undamaged detection, no sample pretreatment, and having a coverage area relatively larger than that of scanning electron microscopy. For spectroscopic ellipsometric data fitting, previous studies usually adopted a four-layer model, which displays a large bias from the raw data. Here, a modified six-layer model is built in consideration of the more elaborate porous layer that is the dominating contributor for the optical property of a PAA film. By using this six-layer model, PAA films with different thicknesses and under different oxidation voltages were analyzed, and the disperse curves of the porous layer were provided. This study will be helpful for learning the subtle structure of PAA and widen its applications for optical purposes.

Uniform, well-dispersed platinum nanoparticles were grown on SrTiO₃ nanocuboids via atomic layer deposition (ALD) using (methylcyclopentadienyl)trimethylplatinum (MeCpPt(Me)₃) and water. For the first half-cycle of the deposition particles formed through two sequential processes: initial nucleation and growth. The final particle size after a single complete ALD cycle was dependent on the reaction temperature which alters the net Pt deposition per cycle. Additional cycles resulted in further growth of previously formed particles. However, the increase in size per cycle during additional ALD cycles, beyond the first, was significantly lower as less Pt was deposited due to carbonaceous material that partially covers the surface and prevents further MeCpPt(Me)₃ adsorption and reaction. The increase in particle size was also temperature dependent due to changes in the net Pt deposition. Pt nanoparticles increased in size by 59% and 76% after 15 ALD cycles for reaction temperatures of 200 °C and 300 °C, respectively. There was minimal change in the number of particles per unit area as a function of reaction time, indicating that there was minimal Ostwald ripening or secondary nucleation for the reaction conditions.

Ion beam milling is the most common modern method for preparing specific features for microscopic analysis, even though concomitant ion implantation and amorphization remain persistent challenges, particularly as they often modify materials properties of interest. Atomic force microscopy (AFM), on the other hand, can mechanically mill specific nanoscale regions in plan-view without chemical or high energy ion damage, due to its resolution, directionality, and fine load control. As an example, AFM-nanomilling (AFM-NM) is implemented for top-down planarization of polycrystalline CdTe thin film solar cells, with a resulting decrease in the root mean square (RMS) roughness by an order of magnitude, even better than for a low incidence FIB polished surface. Subsequent AFM-based property maps reveal a substantially stronger contrast, in this case of the short-circuit current or open circuit voltage during light exposure. Electron back scattering diffraction (EBSD) imaging also becomes possible upon AFM-NM, enabling direct correlations between the local materials properties and the polycrystalline microstructure. Smooth shallow-angle cross-sections are demonstrated as well, based on targeted oblique milling. As expected, this reveals a gradual decrease in the average short-circuit current and maximum power as the underlying CdS and electrode layers are approached, but a relatively consistent open-circuit voltage through the diminishing thickness of the CdTe absorber. AFM-based nanomilling is therefore a powerful tool for material characterization, uniquely providing ion-damage free, selective area, planar smoothing or low-angle sectioning of specimens while preserving their functionality. This enables novel, co-located advanced AFM measurements, EBSD analysis, and investigations by related techniques that are otherwise hindered by surface morphology or surface damage.