Entanglement may be considered a resource for quantum information
processing, as the origin of robust and universal equilibrium
behaviour, but also as a limit to the validity of an effective
potential approach, in which the influence of certain interacting
subsystems is treated as a potential. Here we show that a closed
three-particle (two protons, one electron) model of a
He+-ion featuring realistic size, interactions and energy
scales of electron and nucleus, respectively, exhibits different
types of dynamics depending on the initial state: For some cases
the conventional approach, in which the nucleus only appears as the
center of a Coulomb potential, is valid, in others this approach
fails due to entanglement arising on timescales as small as
10−5s. Eventually, the system can even show signatures of
thermodynamical behaviour, i.e. the electron may relax to
a maximum local entropy state which is, to some extent, independent
of the details of the initial state.