We show, using surface pressure vs. molecular area isotherm measurements
and synchrotron grazing X-ray diffraction, that 4BCD12 molecules, which
consist of a central flexible bowl-like core to which eight long
lateral hydrocarbon chains are bound, form a stable edge-on monolayer. Experimental
data indicate that six lateral hydrocarbon chains orient upwards to form a
quasi-rectangular lattice of 43° tilted hydrocarbon chains. The obtained axially asymmetric phase, which we label
edge26-on, allows using surface potential measurements, for the
validation of literature electric models of a single monolayer spread at the
air-water interface.