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Thermoelectric performance of weakly coupled granular materials

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Published 24 September 2009 Europhysics Letters Association
, , Citation A. Glatz and I. S. Beloborodov 2009 EPL 87 57009 DOI 10.1209/0295-5075/87/57009

0295-5075/87/5/57009

Abstract

We study thermoelectric properties of inhomogeneous nanogranular materials for weak tunneling conductance between the grains, gt<1. We calculate the thermopower and figure of merit taking into account the shift of the chemical potential and the asymmetry of the density of states in the vicinity of the Fermi surface. We show that the weak coupling between the grains leads to a high thermopower and low thermal conductivity resulting in relatively high values of the figure of merit on the order of one. We estimate the temperature at which the figure of merit has its maximum value for two- and three-dimensional samples. Our results are applicable for many emerging materials, including artificially self-assembled nanoparticle arrays.

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10.1209/0295-5075/87/57009