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On the Collapse of Random Copolymers

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Published under licence by IOP Publishing Ltd
, , Citation P. Grassberger and R. Hegger 1995 EPL 31 351 DOI 10.1209/0295-5075/31/7/002

0295-5075/31/7/351

Abstract

We present simulations of a random copolymer model introduced by Kantor and Kardar (Europhys. Lett., 28 (1994) 169). In this model there are two types A, B of monomers. Neighbouring monomers interact with a potential +v0 if they are of the same type, and with −v0 else. When NANB, we find a θ-transition at Tθ close to that found by Kantor and Kardar. But this θ-collapse disappears for smaller values of x = |NA - NB| / (NA + NB) than found by these authors, and we argue that it will be indeed difficult to show convincingly that there exists a finite Tθ for any x ≠ 0. The reason for this difficulty is that the polymer first seems to collapse as N = NA + NB increases, but this collapse stops for large N. This suggests that long chains with x ≠ 0 at low temperatures have a structure different from that proposed for copolymers with long-range interactions.

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10.1209/0295-5075/31/7/002