Abstract
First investigation of the pressure dependence of the pretransitional optical activity in the isotropic liquid of highly chiral liquid crystal CE2 in isothermal regime is reported. The inversion of sign of the solpe of the dependence of the optical rotation on pressure in the isotropic liquid is observed. The experimental data agree well with the theory of the effect, developed in terms of the Landau-de Gennes approach to the description of flucturational phenomena in liquid crystals. Theoretical parameters, describing the process of orientational correlations in the isotropic liquid, are determined.