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Synthesis and characterization of semi-crystalline polyarylene ether nitrile with AIEE feature

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Published under licence by IOP Publishing Ltd
, , Citation Pan Wang et al 2017 IOP Conf. Ser.: Mater. Sci. Eng. 274 012090 DOI 10.1088/1757-899X/274/1/012090

1757-899X/274/1/012090

Abstract

An AIEgen 1, 2-di (4-hydroxyphenyl)-1, 2-diphenylethene (TPE-2OH) was introduced into the back bone of semi-crystalline poly arylene ether nitriles (PEN). The fluorescence spectra results indicated that the derived polymer displayed a typical aggregation-induced emission enhancement (AIEE) active with an emitting peak at ∼470 nm. Then the AIEE active PEN was prepared into films through casting method and realised strong fluorescence emission and excellent mechanics properties. Besides, the crystal AIEE active polymer shows sphere micro-morphology along with a strong blue emission. These findings will open a door for further research on the high performance semi-crystalline PEN at flexible display technology and optical sensors.

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10.1088/1757-899X/274/1/012090