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The synthesis of novel thiol/amino bifunctionalized SBA-15 and application on the Cr(VI) absorption

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Published under licence by IOP Publishing Ltd
, , Citation Y Yang et al 2017 IOP Conf. Ser.: Earth Environ. Sci. 82 012074 DOI 10.1088/1755-1315/82/1/012074

1755-1315/82/1/012074

Abstract

Novel amino/thiol organic groups modified SBA-15 materials were successfully prepared by a simple co-condensation approach. The synthesize mesoporous materials were characterized by FT-IR, SAXRD, N2 adsorption and elemental analysis (EA). The absorption behavior of Cr (VI) in the samples has been investigated. The experiments revealed that the adsorption amount of Cr (VI) was decided by thiol groups, but the adsorption equilibrium time was mainly effected by amino groups. The 15% NH2+20%SH sample had the best adsorption performance. Its maximum adsorption capacity can be up to 49.29 mg/g at the optimum conditions. The research of adsorption mechanism including adsorption kinetics and adsorption thermodynamics was also presented.

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10.1088/1755-1315/82/1/012074