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Ultra accurate measurements and ab initio calculations of collisional effects in pure D2.

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Published under licence by IOP Publishing Ltd
, , Citation Mikołaj Zaborowski et al 2017 J. Phys.: Conf. Ser. 810 012042 DOI 10.1088/1742-6596/810/1/012042

1742-6596/810/1/012042

Abstract

We present our experimental spectra of the very weak S(2) transition from the 2–0 band of molecular deuterium, measured with a frequency-stabilized cavity ring-down spectroscopy (FS–CRDS) assisted by the optical frequency comb (OFC). Experimental collisional broadening and shifting are compared with results of ab initio quantum scattering calculations.

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10.1088/1742-6596/810/1/012042