Synopsis
We have measured the Recoil Frame - Photoelectron Angular Distributions (RF-PADs) for inner-shell photoionization of CH3F, CH3I and CF3I halomethane molecules for photoelectron energies up to 300 eV detected within a 4π solid angle in the gas-phase. For high kinetic energies, the RF-PADs are dominated by diffraction effects that encode information on the molecular geometry.
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