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The following article is Open access

Dynamics and energetics of photoion-pair formation in HF/DF

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Published under licence by IOP Publishing Ltd
, , Citation Q J Hu and J W Hepburn 2005 J. Phys.: Conf. Ser. 4 267 DOI 10.1088/1742-6596/4/1/040

1742-6596/4/1/267

Abstract

Preliminary results of a high resolution coherent vacuum ultraviolet study of photoion-pair formation in HF/DF are reported. These results include threshold ion-pair production (TIPPS) and total photoion-pair yield spectra, which show sharp resonances due to predissociating Rydberg states. Detailed analysis of the spectra provides precise energies for the ion-pair thresholds, and insight into the mechanism for ion-pair formation.

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10.1088/1742-6596/4/1/040