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Theoretical investigation of Rydberg and doubly-excited states of molecular hydrogen: The halfium model

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Published under licence by IOP Publishing Ltd
, , Citation Mourad Telmini et al 2005 J. Phys.: Conf. Ser. 4 256 DOI 10.1088/1742-6596/4/1/038

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1 LSAMA Department of Physics, Faculty of Sciences of Tunis, University of Tunis El Manar, 2092 Tunis, Tunisia

2 Laboratoire Aimé Cotton du CNRS, Université de Paris-Sud, 91405 Orsay, France

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1742-6596/4/1/256

Abstract

The halfium model is presented and its application to 1Σ+g ionization channels of H2 is described. Ab initio calculations of the (2pσ)2 doubly excited state of H2 are presented and compared with previous calculations. The connection with a fully ab initio study of the H2 dissociative recombination process is outlined.

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10.1088/1742-6596/4/1/038