We present first-principles calculations of the bonding properties for the series of boron compounds BP, BAs, and BSb. The plane-wave pseudopotential approach to density functional theory in the local density approximation has been used to calculate the equilibrium properties, i.e., the ground-state energy, the lattice constant, the bulk modulus, its pressure derivative, and the ionicity factor. The valence electron density is used to study the modification of the bonding with respect to different pressures. The calculated electronic charge densities present an anomalous behaviour which can be characterized by reversing the standard assignments for the anion and cation in these compounds. The competition between the ionic and the covalent character in these materials is discussed in relation to the charge transfer. Estimates of the ionicity and its pressure derivative for the series of boron compounds are presented. The distribution of the valence charge density suggests that the bonding in these materials is less ionic than in other zinc-blende compounds.