Excitation dynamics and post-collision interaction for lowest autoionizing states in Li and Li₂ excited by electron impact

The ejected-electron spectra in the region of the lowest autoionizing states in Li and have been studied at an observation angle of 54.7° over the electron-impact energy range 0–6 eV above the excitation threshold at 56.4 eV. The strong near-threshold resonance excitation has been revealed for the and (1s → 3σ_g)¹Σ⁺_g molecular transitions. For the atomic , and molecular states the post-collision interaction (PCI) energy shift of corresponding lines has been measured and compared with electron-impact excitation functions for these states. The general appearance of the PCI data for the and states reveals a close agreement with the classical and semi-classical predictions, showing a minimal correlation between resonance excitation of the subshell and the PCI. Meanwhile, in the energy region of 0–1 eV the energy shift of the line reveals an abrupt decrease to nearly zero values, similar to that observed earlier for the (np⁵(n+1)s²)²P_3/2 lines in the ejected-electron spectra of Na (n = 2) and K (n = 3) atoms. The calculations show the possibility for extrema of the PCI shift to appear in those energy regions where the negative-ion resonances are present in the excitation function of the state.