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A lattice model of hydrogen bonding in mixtures. I. General formulation in terms of weak subgraphs

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Published under licence by IOP Publishing Ltd
, , Citation A Bellemans et al 1985 J. Phys. A: Math. Gen. 18 3567 DOI 10.1088/0305-4470/18/18/018

0305-4470/18/18/3567

Abstract

A particular version of the lattice model of Abraham and Heilmann (1972) for hydrogen-bonded systems is worked out by means of a weak subgraph expansion. Each site may be occupied by one molecule, A or B, and two neighbouring molecules. A may bind together, as far as neither of them is already engaged in more than one bond. It turns out that, for a wide range of the parameters involved in the model, the zeroth approximation (replacement of the true lattice by a Bethe lattice) leads to reasonable values of its thermodynamic properties.

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