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MCC/IMS signals in human breath related to sarcoidosis—results of a feasibility study using an automated peak finding procedure

A Bunkowski1, B Bödeker1, S Bader1, M Westhoff2, P Litterst2 and J I Baumbach1

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A feasibility study using an ion mobility spectrometer coupled with a multi-capillary column (MCC) was started to identify characteristic peaks of volatile compounds in exhaled human breath samples of 10 ml volume. The breath of 20 patients with sarcoidosis and suspicion of sarcoidosis because of mediastinal lymph node enlargement was investigated. Using a set of procedures for data processing and scoring a sector of interest was determined within the IMS-chromatogram. It could be shown that a procedure related to a single peak in the IMS-chromatogram delivers differentiation into the two groups of patients with confirmed sarcoidosis and those suffering no sarcoidosis. The potential biomarker is characterized by the following parameters: inverse mobility (1/K0) 0.53 ± 0.01 V s cm−2—retention time 22 ± 5 s. These results are a first step in breath analysis by MCC/IMS in patients with sarcoidosis by an automated procedure applied to IMS-chromatograms directly.


PACS

87.80.-y Biophysical techniques (research methods)

82.80.Bg Chromatography

87.19.X- Diseases

87.19.U- Hemodynamics

Subjects

Instrumentation and measurement

Medical physics

Biological physics

Chemical physics and physical chemistry

Dates

Issue 4 (December 2009)

Received 15 February 2009, accepted for publication 11 August 2009

Published 23 September 2009



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