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Thermodynamics as a nonequilibrium path integral

Poulomi Sadhukhan and Somendra M Bhattacharjee

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Thermodynamics is a well-developed tool to study systems in equilibrium but no such general framework is available for nonequilibrium processes. The only hope for a quantitative description is to fall back upon the equilibrium language as often done in biology. This gap is bridged by the work theorem. By using this theorem, we show that the Barkhausen-type nonequilibrium noise in a process, repeated many times, can be combined to construct a special matrix {\cal S} whose principal eigenvector provides the equilibrium distribution. For an interacting system, {\cal S}, the equilibrium distribution can be obtained from the free case without any requirement of equilibrium.


PACS

05.70.Ln Nonequilibrium and irreversible thermodynamics

02.10.Ud Linear algebra

05.20.-y Classical statistical mechanics

05.40.Ca Noise

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

02.10.Yn Matrix theory

MSC

82D40 Magnetic materials

15A18 Eigenvalues, singular values, and eigenvectors

82C05 Classical dynamic and nonequilibrium statistical mechanics (general)

82C80 Numerical methods (Monte Carlo, series resummation, etc.)

82C35 Irreversible thermodynamics, including Onsager-Machlup theory

Subjects

Mathematical physics

Condensed matter: electrical, magnetic and optical

Statistical physics and nonlinear systems

Dates

Issue 24 (18 June 2010)

Received 3 December 2009, in final form 14 April 2010

Published 20 May 2010



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