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First-order dynamical phase transition in models of glasses: an approach based on ensembles of histories

Juan P Garrahan1, Robert L Jack2,3, Vivien Lecomte4,5, Estelle Pitard6, Kristina van Duijvendijk4 and Frédéric van Wijland4

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We investigate the dynamics of kinetically constrained models of glass formers by analysing the statistics of trajectories of the dynamics, or histories, using large deviation function methods. We show that, in general, these models exhibit a first-order dynamical transition between active and inactive dynamical phases. We argue that the dynamical heterogeneities displayed by these systems are a manifestation of dynamical first-order phase coexistence. In particular, we calculate dynamical large deviation functions, both analytically and numerically, for the Fredrickson–Andersen model, the East model, and constrained lattice gas models. We also show how large deviation functions can be obtained from a Landau-like theory for dynamical fluctuations. We discuss possibilities for similar dynamical phase-coexistence behaviour in other systems with heterogeneous dynamics.


PACS

64.70.P- Glass transitions of specific systems

05.50.+q Lattice theory and statistics (Ising, Potts, etc.)

02.50.Ga Markov processes

02.50.Cw Probability theory

05.70.Ce Thermodynamic functions and equations of state

61.43.Fs Glasses

MSC

82B20 Lattice systems (Ising, dimer, Potts, etc.) and systems on graphs

82B26 Phase transitions (general)

82B30 Statistical thermodynamics (See also 80-XX)

60J05 Markov processes with discrete parameter

82B44 Disordered systems (random Ising models, random Schrödinger operators, etc.)

74N20 Dynamics of phase boundaries

Subjects

Computational physics

Condensed matter: structural, mechanical & thermal

Statistical physics and nonlinear systems

Dates

Issue 7 (20 February 2009)

Received 30 October 2008, in final form 15 December 2008

Published 21 January 2009



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