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Stretched polygons in a lattice tube

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M Atapour1, C E Soteros2 and S G Whittington3

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We examine the topological entanglements of polygons confined to a lattice tube and under the influence of an external tensile force f. The existence of the limiting free energy for these so-called stretched polygons is proved and then, using transfer matrix arguments, a pattern theorem for stretched polygons is proved. Note that the tube constraint allows us to prove a pattern theorem for any arbitrary value of f, while without the tube constraint it has so far only been proved for large values of f. The stretched polygon pattern theorem is used first to show that the average span per edge of a randomly chosen n-edge stretched polygon approaches a positive value, non-decreasing in f, as n. We then show that the knotting probability of an n-edge stretched polygon confined to a tube goes to one exponentially as n. Thus as n when polygons are influenced by a force f, no matter its strength or direction, topological entanglements, as defined by knotting, occur with high probability.


PACS

05.50.+q Lattice theory and statistics (Ising, Potts, etc.)

02.50.Cw Probability theory

36.20.-r Macromolecules and polymer molecules

05.70.Ce Thermodynamic functions and equations of state

02.40.-k Geometry, differential geometry, and topology

MSC

82D60 Polymers

82B30 Statistical thermodynamics (See also 80-XX)

51E12 Generalized quadrangles, generalized polygons

Subjects

Soft matter, liquids and polymers

Atomic and molecular physics

Mathematical physics

Computational physics

Statistical physics and nonlinear systems

Dates

Issue 32 (14 August 2009)

Received 29 May 2009, in final form 27 June 2009

Published 21 July 2009



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