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Self-avoiding polygons and walks in slits

J Alvarez1,2, E J Janse van Rensburg2, C E Soteros3 and S G Whittington1

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A polymer in a confined geometry may be modeled by a self-avoiding walk or a self-avoiding polygon confined between two parallel walls. In two dimensions, this model involves self-avoiding walks or self-avoiding polygons in the square lattice between two parallel confining lines. Interactions of the polymer with the confining walls are introduced by energy terms associated with edges in the walk or polygon which are at or near the confining lines. We use transfer-matrix methods to investigate the forces between the walk or polygon and the confining lines, as well as to investigate the effects of the confining slit's width and of the energy terms on the thermodynamic properties of the walks or polygons in several models. The phase diagram found for the self-avoiding walk models is qualitatively similar to the phase diagram of a directed walk model confined between two parallel lines, as was previously conjectured. However, the phase diagram of one of our polygon models is found to be significantly different and we present numerical data to support this. For that particular model we prove that, for any finite values of the energy terms, there are an infinite number of slit widths where a polygon will induce a steric repulsion between the confining lines.


PACS

61.41.+e Polymers, elastomers, and plastics

65.60.+a Thermal properties of amorphous solids and glasses: heat capacity, thermal expansion, etc.

05.40.Fb Random walks and Levy flights

05.50.+q Lattice theory and statistics (Ising, Potts, etc.)

MSC

82B30 Statistical thermodynamics (See also 80-XX)

82B20 Lattice systems (Ising, dimer, Potts, etc.) and systems on graphs

82B41 Random walks, random surfaces, lattice animals, etc. (See also 60G50, 82C41)

82D60 Polymers

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Statistical physics and nonlinear systems

Dates

Issue 18 (9 May 2008)

Received 12 February 2008, in final form 27 March 2008

Published 18 April 2008



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