Abstract
A biopolymer-based template assembly constructed around the spines of the bristle worm Aphrodita aculeata (sea mouse) was used to fabricate very high aspect ratio nanowires and nanotubes using established methods adopted from nanofabrication in porous membranes. The easily available bio-originated template contains more than 100 000 highly ordered, very high aspect ratio nanochannels, each about 150 to 200 nm in diameter but up to a centimetre in length. Their parallel, hexagonal arrangement in the spine constitutes a photonic crystal, which gives the animal its colourful, iridescent appearance. Around the nanochannels, the spines consist of a chitin/protein composite material, which has been shown to withstand the chemical and thermal conditions needed for established template-assisted nanofabrication strategies. A template preparation procedure was developed and the template was used to fabricate copper and nickel nanowires by electrodeposition and aluminium oxide nanotubes by atomic layer deposition. Due to their high thermal and chemical stability, decomposition of the filled templates proved to be difficult, and different approaches to obtain separated nanostructures are described and discussed. Alongside this, the presented system of parallel nanowires or nanotubes in a biopolymer matrix might be utilized in applications, where such separated structures are not needed. Comparing to porous membranes, the presented template allows us to increase the maximum length of nanotubes and nanowires produced using nanochannel-based templates by at least one order of magnitude.
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