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Optical emissions from the dissociative recombination of N2H+, HCO+, HOC+, and HNC+

R Johnsen1, M F Golde2, R E Rosati3, D Pappas4 and M P Skrzypkowski5

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We present recent flowing-afterglow measurements of branching fractions for electronically and vibrationally excited products arising from the dissociative recombination of N2H+, HCO+, HOC+, and HNC+ ions with thermal electrons. State-specific yields were derived by fitting the observed, spatially resolved emission band intensities to models that simulate all ion-chemical processes, recombination, diffusion, and gas mixing.


PACS

34.80.Lx Recombination, attachment, and positronium formation

33.20.Tp Vibrational analysis

Subjects

Atomic and molecular physics

Dates

Issue 1 (2009)



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