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Effect of K3PO4 addition as sintering inhibitor during calcination of Y2O3 nanoparticles

K Soga1,2, Y Okumura1, K Tsuji1 and N Venkatachalam2

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Erbium-doped yttrium oxide nanoparticle is one of the most important for fluorescence bioimaging under near infrared excitation. Particle size of it below 100 nm is an important requirement for a cellular bioimaging. However, the synthesis with such small particles is difficult at the calcination temperature above 1200 °C due to the sintering and crystal growth of the particles. In this study, yttrium oxide nanoparticles with average size of 30 nm were successfully synthesized by using K3PO4 as a sintering inhibitor during the calcination. A single phase of cubic Y2O3 as the resultant material was confirmed by XRD, which was also confirmed to emit a bright upconversion emission under 980-nm excitation. Improvement of chemical durability due to the introduction of phosphate group on the surface of the Y2O3 particles is also reported.


PACS

81.16.-c Methods of nanofabrication and processing

81.20.Ev Powder processing: powder metallurgy, compaction, sintering, mechanical alloying, and granulation

61.46.Df Structure of nanocrystals and nanoparticles ("colloidal" quantum dots but not gate-isolated embedded quantum dots)

87.85.Qr Nanotechnologies-design

42.30.-d Imaging and optical processing

81.40.Gh Other heat and thermomechanical treatments

Subjects

Optics, quantum optics and lasers

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 1 (2009)



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