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Journal of Physics: Conference Series Volume 190 Number 1 Create an alert RSS this journal

W Taweepreda et al 2009 J. Phys.: Conf. Ser. 190 012150 doi:10.1088/1742-6596/190/1/012150

Model compound vulcanization studied by XANES

W Taweepreda1,2, R Nu-Mard1, W Pattanasiriwisawa3 and P Songsiriritthigul3,4

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Abstract References

Squalene has been used as a model compound for the investigation of sulphur crosslink in the vulcanization process. The effects of the accelerator on the crosslink were deduced from the sulfur K-edge absorption spectra. The majority of the crosslinks for the squalene vulcanized with ZDEC or TMTD is likely disulfidic, while that vulcanized with CBS or MBTS is monosulfidic.


PACS

78.70.Dm X-ray absorption spectra

81.05.Lg Polymers and plastics; rubber; synthetic and natural fibers; organometallic and organic materials

Subjects

Soft matter, liquids and polymers

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 1 (2009)



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