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Analysis of the nitrogen K-edge x-ray absorption spectra of Zn-porphyrin/C70-fulleren complex for solar cells

S A Suchkova1, C Castellarin Cudia2 and A Soldatov1

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The atomic structure models of Zn-porphyrin/C70 multilayer for solar cells were examined. The local atomic structure of the Zn-porphyrin/C70 complex was refined with the use of previously published results [1]. Since near-edge spectral region (XANES) is sensitive to the three-dimensional atomic geometry, the theoretical analysis of the experimental XANES was performed on the basis of finite difference method (FDMnes 2008 program code). Some electronic properties of the complex were obtained from the DFT calculations performed by means of Amsterdam Density Functional program package.


PACS

78.70.Dm X-ray absorption spectra

68.65.Ac Multilayers

73.21.Ac Multilayers

84.60.Jt Photoelectric conversion: solar cells and arrays

71.15.Mb Density functional theory, local density approximation, gradient and other corrections

Subjects

Electronics and devices

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 1 (2009)



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