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XANES and photoluminescence studies of crystalline GeO2 (Tb) nanowires

Franziskus Heigl1, Lidia Armelao2,3, X H Jeff Sun3,8, Candice Didychuk3, Xing-Tai Zhou3,4, Tom Regier5, Robert I R Blyth5, P S Grace Kim6, Richard A Rosenberg7 and Tsun-Kong Sham3

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We report a synchrotron study of GeO2 nanowires (NWs) prepared by a vapor- liquid-solid (VLS) method on a silica glass substrate. The electronic and local structure of GeO2 NWs were studied by X-ray Absorption Near-Edge Structure (XANES) at the O K- and Ge L3,2-edges. X-ray Excited Optical Luminescence (energy and time resolved) were used to monitor the optical emission upon X-ray absorption with the excitation energy tuned across absorption edges of interest. Using this method one obtains site specific insight into the chemical origin of luminescence.


PACS

78.70.Dm X-ray absorption spectra

73.22.-f Electronic structure of nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals

78.55.Hx Other solid inorganic materials

78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures

68.65.-k Low-dimensional, mesoscopic, and nanoscale systems: structure and nonelectronic properties

78.47.-p Spectroscopy of solid state dynamics

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 1 (2009)



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