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Broken symmetry of cage surrounding magnetic dopant Cr ion in cubic GaN

S Emura, K Tokuda, S Kobayashi, Y K Zhou, S Hasegawa and H Asahi

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The X-ray absorption spectra around the Cr K-edge are observed to reveal the strange behaviour on the magnetism of the dilute magnetic semiconductor GaCrN with a cubic structure (Fbar 43 m = Td2). The radial distribution function analyzed in the part of the X-ray absorption fine structure shows the splitting in the first and the second nearest neighbours into two peaks, indicating that the Cr ion substitutes the Ga ion but shifts from just the lattice site of the Ga ion. This local lattice instability breaking the symmetry is explained by pseudo-Jahn – Teller effect. In the relation to the local lattice instability, the electronic ground state of the Cr ion in the cubic GaN is discussed.


PACS

78.70.Dm X-ray absorption spectra

75.50.Dd Nonmetallic ferromagnetic materials

75.50.Pp Magnetic semiconductors

71.70.Ej Spin-orbit coupling, Zeeman and Stark splitting, Jahn-Teller effect

71.20.Nr Semiconductor compounds

61.72.uj III–V and II–VI semiconductors

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Condensed matter: structural, mechanical & thermal

Dates

Issue 1 (2009)



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