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Local scale ordering in LaMnO3 under pressure: X-ray absorption study

A Y Ramos1, H C N Tolentino1, N M Souza-Neto2, A Caneiro3, Y Joly1, J P Itié4, A M Flank4 and P Lagarde4

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The present study aims, by using X-ray Absorption Spectroscopy, to describe the local process towards the pressure-induced abrupt changes in the resistivity in the Jahn-Teller distorted LaMnO3 doped compounds. Local environment of manganese atoms under pressure up to 37 GPa has been studied by X-ray absorption spectroscopy. We identify successive steps towards the pressure-induced abrupt changes in the resistivity. These steps are associated to local processes such as the opening of the inter-octahedra tilt angles and the average symmetrization of the Mn local environment. All modifications present a hysteretic behavior when the pressure is released, pointing to the coexistence of MnO6 distorted and undistorted units.


PACS

78.70.Dm X-ray absorption spectra

72.80.Sk Insulators

71.70.Ej Spin-orbit coupling, Zeeman and Stark splitting, Jahn-Teller effect

62.50.-p High-pressure effects in solids and liquids

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 1 (2009)



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