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Local crystalline structure of Sm-Co alloys: Results of XAFS-analysis

A P Menushenkov1, V P Menushenkov2, R V Chernikov1, T A Sviridova2, O V Grishina1, V V Sidorov1 and K V Klementiev3

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Local crystalline structure of hypo- and hyperstoichiometric SmCox alloys with x = 5.15, 4.95, 4.0, 3.75 heat treated in different conditions was investigated by means of the X-ray absorption spectroscopy. Experimental spectra were measured above the L3-Sm absorption edge. EXAFS-analysis shows that stacking faults appear in hyperstoichiometric alloys SmCo4 and SmCo3.75, confirming the hypothesis of "high coercive state, induced by phase transformations, changing the state of the grain surface in basic phase". L3-Sm XANES spectra demonstrate the reduction of the "white line" amplitude in Sm-enriched samples.


PACS

61.66.Dk Alloys

61.05.cj X-ray absorption spectroscopy: EXAFS, NEXAFS, XANES, etc.

78.70.Dm X-ray absorption spectra

75.50.Vv High coercivity materials

61.72.Nn Stacking faults and other planar or extended defects

75.60.Ej Magnetization curves, hysteresis, Barkhausen and related effects

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 1 (2009)



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