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UV-visible emission as a probe of core excitations applied to the furan and carbon dioxide molecules

A Kivimäki1, M Coreno1,2, J Álvarez Ruiz3, M de Simone1, M Dampc4 and M Zubek4

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The core excitations of the furan and carbon dioxide molecules have been studied using dispersed UV-visible fluorescence spectroscopy. Balmer-α (Balmer-β) emission was measured at the O 1s and C 1s (O 1s) excitations of furan, while emission due to an excited state of the neutral oxygen atom was measured at the O 1s excitations of CO2. The excitation functions of the emission lines display both valence and Rydberg resonances, but the latter are more enhanced.


PACS

33.50.Dq Fluorescence and phosphorescence spectra

33.80.Rv Multiphoton ionization and excitation to highly excited states (e.g., Rydberg states)

Subjects

Atomic and molecular physics

Dates

Issue 1 (2009)



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