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The electronic structure in 3d transition metal complexes: Can we measure oxidation states?

Pieter Glatzela, Grigory Smolentsevb and Grant Bunkerc

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We discuss the information on the electronic structure that can be obtained by K-shell absorption and emission spectroscopy in systems that contain 3d transition metals. We remind the reader that the chemical sensitivity of the X-ray absorption near edge structure (XANES) is strongly influenced by the local geometry. The X-ray fluorescence is mostly sensitive to the electronic structure and thus complementary to XANES.


PACS

71.20.Rv Polymers and organic compounds

78.70.Dm X-ray absorption spectra

82.80.Ej X-ray, Mössbauer, and other gamma-ray spectroscopic analysis methods

78.70.En X-ray emission spectra and fluorescence

Subjects

Soft matter, liquids and polymers

Condensed matter: electrical, magnetic and optical

Chemical physics and physical chemistry

Dates

Issue 1 (2009)



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