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Enhanced photocatalytic properties of quantum-sized ZnO induced by La3+-Nd3+ co-doping

S X Lu, T Zhu and W G Xu

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Nanoparticles of ZnO doped with La3+, Nd3+, co-doped with La3+ and Nd3+ were prepared using the sol-gel method. The samples were characterized by means of X-ray diffraction (XRD), UV-Vis spectroscopy (UV). The photocatalytic reactivities were evaluated by photodegradation of unsymmetrical dimethylhydrazine solution. Nanocrystalline ZnO co-doped with La3+ and Nd3+ at optimal concentration (2 at.% La3+ and 1.5 at.% Nd3+) shows a better synergistic effect, which significantly increases the photodegradation activity of nano-ZnO. The factors influencing photoreactivity of co-doped nanocrystalline ZnO have been discussed.


PACS

82.65.+r Surface and interface chemistry; heterogeneous catalysis at surfaces

61.72.uj III–V and II–VI semiconductors

81.16.-c Methods of nanofabrication and processing

78.67.Bf Nanocrystals and nanoparticles

82.50.Hp Processes caused by visible and UV light

81.20.Fw Sol-gel processing, precipitation

Subjects

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Condensed matter: structural, mechanical & thermal

Chemical physics and physical chemistry

Dates

Issue 1 (2009)



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